The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The results he obtained as regards the fine structure of the hydrogen
lines agree with observation inside the limit of experimental error.
Although Sommerfeld’s methods have also been very fruitful when applied
to the spectra of other elements, they were still of a purely formal
and rather arbitrary nature; it is, therefore, of great importance that
the Leiden professor, Ehrenfest, and Bohr succeeded later in handling
the problem from a more fundamental point of view, Bohr making use of
the correspondence principle previously mentioned. It should be said
here, by way of suggestion, that Bohr used the fact that the motions of
the electrons are not simple periodic but “multiple periodic.” We see
this most simply if we think of the revolution of the electrons in the
elliptical orbit as representing one period, and the rotation for the
major axis of the ellipse as representing a second period.
[Illustration: FIG. 27.—The model of the hydrogen atom with stationary
orbits corresponding to principal quantum numbers and auxiliary quantum
numbers.]
Fig. 27 shows a number of the possible stationary orbits in the
hydrogen atom according to Sommerfeld’s theory; for the sake of
simplicity the orbits are drawn as completely closed ellipses. If we
examine, for instance, the orbits with principal quantum number 4,
we have here three more or less elongated ellipses, 4₁, 4₂, 4₃, and
the circle 4₄; in all of them the major axis has the same length,
and the length of the major axis is to that of the minor axis as the
principal quantum number is to the auxiliary quantum number (for the
circle 4 : 4 = 1). On the whole, to a principal quantum number _n_
there correspond the auxiliary quantum numbers 1, 2 ... _n_, and
the orbit for which the auxiliary quantum number equals the principal
quantum number is a circle. We see that in the more complicated
hydrogen atom model there is possibility for a much greater number of
different transitions than in the simple model (Fig. 25, p. 119). Some
of the transitions are indicated by arrows. Since the energy content of
the atom is almost the same for orbits with the same principal quantum
number and different auxiliary quantum numbers, three transitions
like 3₃-2₂, 3₂-2₁ and 3₁-2₂ will give about the same frequency, and
therefore spectral lines which lie very close together. In a transition
like 4₄-4₃ the emitted energy quantum _h_ν, and also ν, will be so
extremely small that the corresponding line will be too far out in the
infra-red for any possibility of observing it.
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