The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
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The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
It must be pointed out that the above considerations only hold if
the hydrogen atoms, strictly speaking, are undisturbed. Thus, very
small external forces, which may be due to the neighbourhood of other
atoms, etc., will be sufficient to cause changes in the eccentricity
of the stationary orbits. In such a case the above definition of the
auxiliary quantum number becomes obviously illusory, and the original
character of the fine structure disappears. This is in agreement with
the experiments, since the Sommerfeld fine structure can be found only
when the conditions in the discharge tube are especially quiet and
favourable.
Influence of Magnetic and Electric Fields on the Hydrogen Lines.
[Illustration: FIG. 28.—The splitting of three hydrogen lines under the
influence of a strong electric field.]
As previously mentioned (p. 76), the spectral lines are split into
three components when the atoms emitting lights are exposed to magnetic
forces. The agreement found here between observation and the Lorentz
electron theory was considered as strong evidence of the correctness
of the latter. According to the Bohr theory, the picture upon which
this explanation rested must be abandoned entirely; but fortunately it
has been shown that the Bohr theory leads to the same results; and,
moreover, Bohr, with the assistance of the correspondence principle,
has been able to set forth the more fundamental reason for this
agreement.
The German scientist, Stark, showed, in 1912, that hydrogen lines are
also split by electric fields of force. In Fig. 28 it is shown how
very complicated this phenomenon is; here the classical electron
theory could not at all explain what happened. This phenomenon
could also be accounted for by the extended Bohr theory (with the
introduction of more than one quantum number), as it was shown
independently by Epstein and by Schwarzschild in 1916; further, the
correspondence principle has again shown its superiority, since
it makes possible an approximate determination of the different
intensities of the different lines. A calculation carried out by H. A.
Kramers has shown that the theory gives a remarkably good agreement
with the experiments.
Not until we think of the extraordinary accuracy of the measurements
which are obtained by spectrum analysis, can we thoroughly appreciate
the importance of the quantitative agreement between theory and
observation in the hydrogen spectrum that has just been mentioned.
Moreover, we must remember how completely helpless we previously were
in the strange puzzles offered even by the simplest of all spectra,
that of hydrogen.
CHAPTER VI
VARIOUS APPLICATIONS OF THE BOHR THEORY
Introduction.
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