The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
where K has about the same value as in hydrogen, and α can take on a
series of values α₁, α₂ ... αₖ, while _n_ takes on integer values.
Since we thus determine the different lines by assigning values to
the two integers _n_ and _k_ in each term, we have in this
respect something like the fine structure in the hydrogen spectrum,
where the stationary states are determined by a principal quantum
number and an auxiliary quantum number. The spectra of which we are
speaking here, and for which the terms have the form given above, are
often called _arc spectra_, because they are emitted particularly
in the light from the electric arc or from the vacuum tube. We must
expect that the similarity which exists in the law for the distribution
of spectral lines will correspond to a similarity in the atomic
processes of hydrogen and the other elements.
The hydrogen atom emits radiation corresponding to the different
spectral lines when an electron from an outer stationary orbit jumps,
with a spring of varying size, to an orbit with lower number, and at
last finds rest in the innermost orbit in a normal state, where the
energy of the atom is as small as possible. Similarly, we must assume
that the electrons in other atoms, during processes of radiation, may
proceed in towards the nucleus until they are collected as tightly
as possible about the nucleus, corresponding to the normal state of
the atom, where its energy content is as small as possible: “capture”
of electrons by the nucleus. The region in space which, in the normal
state, includes the entire electron system, must be assumed to be of
the same order of magnitude as the dimensions of the atom and molecule
which are derived from the kinetic theory of gases. This normal state
may be called a “quiescent” state, since the atom cannot emit radiation
until it has been excited by the introduction of energy from without.
This excitation process consists of freeing one (or more) electrons,
in some way or other, from the normal state and either removing it
out to a stationary orbit farther away from the nucleus or ejecting
it completely from the atom. Not all electrons can be equally easily
removed from the quiescent state. Those moving in small orbits near
the nucleus will be tighter bound than those moving in larger orbits
farther from the nucleus. The arc spectrum is now caused by driving one
of the most loosely bound electrons out into an orbit farther from the
nucleus or removing it completely from the atom. In the latter case
the rest of the atom, which with the loss of the negative electron
becomes a positive ion, easily binds another electron, which, with the
emission of radiation, corresponding to lines of the series spectrum,
can approach closer to the nucleus.
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