The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
Let us now assume, first, that this radiating electron moves at so
great a distance from the nucleus and the other electrons that the
entire inner system can be considered as concentrated in one point;
then the situation is quite as if we had to deal with a hydrogen
atom. If the atomic number is as high as 29 (copper), for instance,
the nuclear charge will consist of twenty-nine elementary quanta of
positive electricity; but since there are twenty-eight electrons in
the inner system, the resultant effect is that of only one elementary
quantum of positive electricity, as in the case of a hydrogen nucleus.
The spectral lines which are emitted in the jumps between the more
distant paths will be practically the same as hydrogen lines.
But, since in the jumps between these distant orbits, very small
energy quanta will be emitted, the frequencies are very small, the
wave-lengths very great, _i.e._, the lines in question lie far out
in the infra-red.
[Illustration: FIG. 29.—Different stationary orbits which the outermost
(11th) electron of sodium may describe.]
When the electron has come in so close to the nucleus that the
distances in the inner system cannot be assumed to be small in
comparison to the distance of the outer electron from the nucleus,
the situation is changed. The force with which the nucleus and the
inner electrons together will work upon the outer electron will be
appreciably different from the inverse square law of attraction of a
point charge. The consequence of this difference is that the major
axis in the ellipse of the electron rotates slowly in the plane of the
orbit as described in case of the theory of the fine structure of the
hydrogen lines (cf. p. 146), and even if the cause is different the
result is the same; the orbit of the outer electron in the stationary
states will be characterized by a quantum number _n_ and an
auxiliary quantum number _k_. If the electron comes still closer
to the nucleus, its motion is even more complicated. When the electron
in its revolution is nearest the nucleus it will be able to dive into
the region of the inner electrons, and we can get motions like those
shown in Fig. 29 for one of the eleven sodium electrons. The inner
dotted circle is the boundary of the inner system which is given by the
nucleus and the ten electrons remaining in the “quiescent” state—little
disturbed by the restless No. 11. In the figure we can see greater or
smaller parts of No. 11’s different stationary orbits with principal
quantum numbers 3 and 4. We shall not account further for the different
orbits and the spectral lines produced by the transitions between
orbits, but shall merely remark that the yellow sodium line, which
corresponds to the Fraunhofer D-line (cf. p. 49), is produced by the
transition 3₂-3₁, between two orbits with the same principal quantum
number. The sketch shows to a certain degree how fully many details of
the atomic processes can already be explained. The theory can even give
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