The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
It may be asked what becomes of the energy which the hydrogen chloride
molecule thus absorbs, and whether it necessarily after a longer or
shorter time must be re-emitted as radiation. The latter is not the
case. In a collision between molecules or atoms, the energy which
one molecule (or atom) has absorbed by radiation can undoubtedly be
transferred to another molecule, the velocity of which is thereby
increased. The theoretical necessity of the occurrence of such
collisions was clearly shown for the first time in a very significant
investigation by two of Bohr’s students, Klein and Rosseland. Without
collisions of this nature the radiation energy absorbed could never
be transformed into heat energy. Here we come to a very great and
important field, which has a very close connection with the theory of
the chemical processes and to a better explanation of which the more
recent experiments of Franck and his co-workers have made important
contributions.
CHAPTER VII
THE STRUCTURE OF THE ATOM AND THE CHEMICAL PROPERTIES OF THE ELEMENTS
Introduction.
We have hitherto restricted ourselves mainly to those applications of
the Bohr theory which have a direct connection with the processes of
radiation. We have shown how fertile the theory has proved to be, how
many problems, previously inexplicable, have been solved, and what
exact agreement has been established between experiment and theory in
this comprehensive field. We may now ask how the theory accounts for
the chemical behaviour of the different elements. As early as 1913,
Bohr, in connection with his researches on spectral phenomena, had
considered the chemical properties of the elements and had pointed out
interesting possibilities.
[Illustration: FIG. 33.—Early representation of the formation of a
hydrogen molecule (Bohr, 1913).]
The Combination of Atoms into Molecules.
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