The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
In his discussion of hydrogen, Bohr suggested a model for the structure
of its molecule, which we shall give here, because, by a simple
example, it illustrates how two neutral atoms may form a molecule
(cf. p. 13). In Fig. 33, _a_, _K₁E₁_ and _K₂E₂_ are
two neutral hydrogen atoms which are approaching each other with the
orbits of the two electrons parallel. The nucleus _K_₁ and the
electron _E_₂ then attract each other as do the nucleus _K_₂
and the electron _E_₁. The two electrons repel each other as do
the two nuclei; but when the electrons are in opposite positions of
their orbits, the forces of attraction outweigh the effect of the
forces of repulsion. Calculation shows that when the atoms are allowed
to approach each other the positions of the atoms will be as is shown
in Fig. 33, _b_, where the orbits are closer to each other than
the nuclei. Finally, for small distances of the two nuclei, the two
orbits will be merged into one, as is shown in Fig. 33, _c_.
This orbit will be slightly larger than the original ones. The two
hydrogen atoms may, in this way, combine into one molecule. In fact,
an equilibrium position can be found for which the nuclei are held
together, in spite of their mutual repulsion, by the attractive forces
existing between them and the electrons which are moving in their
common orbit. It must, however, be assumed, for reasons which cannot
be given here, that the hydrogen molecule is, in reality, constructed
somewhat differently; probably the orbits of the electrons make an
angle with each other.
The formation of a hydrogen molecule may also be supposed to occur
when a positive hydrogen ion, _i.e._, a hydrogen nucleus, and
a negative hydrogen ion, _i.e._, a hydrogen nucleus with two
electrons, are drawn together by their mutual attractions. The forces
of attraction would be much stronger than in the first example given,
and the formation of a neutral molecule would not take place in the
same way. More energy would also be released, but the final result will
be the same.
Just as in the case of the hydrogen molecule, other molecules may be
formed from atoms belonging to the same or to different elements. The
method of formation of molecules varies according as it is a union
of neutral molecules in the normal state, or a union of positive and
negative ions. Conversely, by chemical decomposition a molecule can be
separated either into neutral parts or into ions. If, for instance,
common salt (sodium chloride, NaCl) is dissolved in water, the salt
molecules are, under the influence of the water molecules, decomposed
in Na-ions with one positive charge and Cl-ions with one negative
charge, corresponding to the monovalent electropositive character of
sodium and the monovalent electronegative character of chlorine.
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