The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The possibilities are, however, far from being exhausted by these two
methods of composition and decomposition. An atom may exist not only
in the normal state where it has its complete number of electrons
collected as tightly as possible about the nucleus, and in the ionized
state with one or more too many or too few electrons; but in a neutral
atom one or more of the outer electrons may be in a stationary orbit
at a greater distance from the nucleus than corresponds to the normal
stationary state. It is easy to understand that an atom in such an
“excited” or (as it is called in chemistry) _active_ state often
finds it easier to act in concert with other atoms than when it is in
the normal state; in this latter state the atom is often more like a
little compact lump of neutral substance than in the active state.
It will, in any case, be understood that the interplay between the
atoms, which reveals itself in the chemical processes or reactions
between different elements, offers many opportunities for the Bohr
theory to give in the future a more detailed explanation than was
possible to the earlier theories of chemistry. We must also mention
the fact that it has become possible to elucidate in main features
the phenomena, hitherto unexplained, of the chemical effects of
light, as on a photographic plate (_photochemistry_) and of
_catalysis_, which consists in bringing about, or accelerating,
the chemical interaction between two substances by the presence of a
third substance which does not itself enter in the compound, and often
needs only to be present in very small quantities. It must, however, be
emphasized that at present we do not yet possess a detailed theory of
molecular constitution comparable with our knowledge of the structure
of the atoms.
The Periodic System.
Instead of inquiring how the chemical processes may take place, we
shall now study the general correlation between the chemical properties
and the atomic numbers of the elements, a correlation which has found
its empirical expression in the natural or periodic system of the
elements (cf. p. 23). The explanation of the puzzles of this system
must be said to be one of the finest results which Bohr has obtained,
and it constitutes a striking evidence in favour of the quantum theory
of atoms.
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