The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The curves drawn represent parts of the orbital loops of the electrons
in the neutral atoms of different elements. Although the attempt has
been made to give a true picture of these orbits as regards their
dimensions, the drawings must still be considered as largely symbolic.
Thus in reality the orbits do not lie in the same plane, but are
oriented in different ways in space. It would have been impracticable
to show the different planes of the orbits in the figure. Moreover,
there is still a good deal of uncertainty as to the relative positions
of these planes. On this account the orbits belonging to the same
sub-group, _i.e._, designated by the same quantum numbers, are
placed in a symmetric scheme in the sketch. For groups of circular
orbits the rule has been followed to draw only one of them as a
circle, while the others in the simpler atoms are drawn in projection
as ellipses within the circle, and in the more complicated atoms are
omitted entirely. The two circular orbits of the helium atom are both
drawn in projection as ellipses. Further, for the sake of clearness,
no attempt has been made to draw the inner loops of the non-circular
orbits of electrons which dive into the interior of the atom. In
lithium only, the inner loop of the orbit of the 2₁ electron has been
shown by dotted lines.
In order to distinguish the groups of orbits with different principal
quantum numbers two colours have been used, red and black, the red
indicating the orbits with uneven quantum numbers, as 1, 3, 5, the
black those with even quantum numbers, as 2, 4, 6. Wherever possible
the nucleus is indicated by a black dot; but in the sketches of atoms
with higher atomic numbers the 1-quantum orbits are merged into one
little cross and the nucleus has been omitted. It should be noticed
that the radium atom is drawn on a scale twice as great as that for the
other atoms.
We shall begin with the capture of the first electron. If the nucleus
is a hydrogen nucleus the _hydrogen atom_ is completed when the
electron has come into the 1₁ orbit, a circle with diameter of about
10⁻⁸ cm. (cf. the diagram). If the nucleus had had a greater nuclear
charge the No. 1 electron would have behaved in the same way, but the
radius of its orbit would have been less in the same ratio as the
nuclear charge was greater. For a lead nucleus, with charge (atomic
number) 82, the radius of the 1₁ orbit is ¹/₈₂ that of the hydrogen 1₁
orbit. Since atoms with high atomic numbers thus collect the electrons
more tightly about them it is understandable that, in spite of their
greater number of electrons, they can be of the same order of magnitude
as the simpler atoms.
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