The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
Let us now examine the _helium atom_. The first electron, which
its nucleus (charge 2) catches, moves as shown in a circle 1₁, but
with a smaller radius than in the case of the hydrogen atom. Electron
No. 2 can be caught in different ways, and the closer study of the
conditions prevailing here, which are still comparatively simple since
there are only two electrons, has been of greatest importance in the
further development of the whole theory. We cannot go into it here, but
must content ourselves with saying that the stable final result of the
binding of the second electron consists in the two electrons moving in
circular 1-quantum orbits of the same size with their planes making
an angle with each other (cf. the diagram). This state has a very
stable character, and the helium atom is therefore very disinclined to
interplay with other atoms, with other helium atoms as well as with
those of other elements. Helium is therefore monatomic and a chemically
inactive gas.
In all atomic nuclei with higher charges than the helium nucleus the
first two orbits are also bound into two 1-quantum circular orbits at
an angle with each other; this group cannot take up any new electron
having the same principal quantum number. It takes on an independent
existence and forms the innermost electron group in all atoms of atomic
number higher than 2.
Electron No. 3 will accordingly not be bound in the same group with
1 and 2. It must be satisfied with a 2-quantum orbit, 2₁, which
consists of oblong loops, and, when nearest the nucleus, comes into the
territory of the 1-quantum orbits. It is but loosely bound compared
to the first two electrons, and the lithium atom, which has only
three electrons, can therefore easily let No. 3 loose so that the
atom becomes a positive ion. _Lithium_ is therefore a strongly
electropositive monovalent metal. The element _beryllium_ (No. 4)
will probably have two electrons in the orbits 2₁; it will therefore be
divalent. But during the short visit of these electrons to the nucleus
they are subject to a greater nuclear charge than in lithium. The 2₁
electrons are therefore, in beryllium, more firmly bound than in
lithium, and the electropositive character of beryllium is therefore
less marked.
We have something essentially new in the _boron_ atom (atomic No.
5) where the two electrons No. 3 and No. 4 are taken into 2₁ orbits,
but where No. 5 will very probably be bound in a circular 2₂ orbit.
How the conditions will be in the normal state of the following atoms
preceding neon is not known with certainty. We only know that the
electrons coming after the first two will be captured in 2-quantum
orbits, the dimensions of which get smaller, according as the atomic
number increases.
Public-domain text, read in full here on John Shaqi.
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