The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
On close examination it becomes evident that the regularity in the
system is not entirely simple. First of all some cases will be found
where the atomic weight of one element is greater than that of the
following element. (The cases of argon and potassium on the one hand
and cobalt and nickel on the other are examples.) Such an interchange
is absolutely necessary if the elements which belong to the same
chemical family are to be placed in the same column. As a second
instance of irregularity, attention must be called to Column VIII. in
the table. While in the first score or so of elements it is always
found that two successive elements have different properties and
clearly belong to distinct chemical families, in the so-called iron
group (iron, cobalt and nickel) we meet with a case where successive
elements resemble each other in many respects (for instance, in their
magnetic properties). Since there are two more such “triads” in the
periodic system, however, we cannot properly call this an irregularity.
But in addition to these difficulties there is what we may even
call a kind of inelegance presented by the so-called “rare earths”
group. In this group there follow after lanthanum thirteen elements
whose properties are rather similar, so that it is very difficult to
separate them from each other in the mixtures in which they occur in
the minerals of nature. (In the table these elements are enclosed in a
frame.)
On the other hand, the apparent absence of an element in certain places
in the table (indicated by a dash) cannot by any means be looked upon
as irregular. In Mendelejeff’s first system there were many vacant
spaces. With the help of his table Mendelejeff was, to some extent,
able to predict the properties of the missing elements. An example of
this is the case of the element between gallium and arsenic. This is
called germanium, and was discovered to have precisely the properties
which had been predicted for it—a discovery which was one of the
greatest triumphs in favour of the reality of the periodic system. On
the whole, the elements discovered since the time of Mendelejeff have
found their natural positions in the table. This is seen, for example,
in the case of the so-called “inactive gases” of the atmosphere,
helium, argon, neon, xenon, krypton and niton, which have the common
property of being able to form no chemical combinations whatever.
Their valence is therefore zero, and in the table they are placed by
themselves in a separate column headed with zero.
To explain the mystery of the periodic system, it was necessary to
make clear not only the regularity of it, but also the apparent
irregularities which seemed to be arbitrary individual peculiarities of
certain elements or groups. In the periodic system, chemistry laid down
some rather searching tests for future theories of atomic structure.
THE PERIODIC OR NATURAL SYSTEM OF THE ELEMENTS
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account