The atom and the Bohr theory of its structure : $b an elementary presentation — John Shaqi
The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The mechanical theory of heat is very useful when we restrict ourselves
to the transfer of heat from one body to another, which is in contact
with it. When applied to gases the theory leads directly to Avogadro’s
Law. If two masses of gas have the same temperature, _i.e._,
if no exchange of heat between them takes place even if they are
in contact with each other, then the average value of the kinetic
energy of the molecules must be the same in both gases. If one gas is
hydrogen and the other oxygen, the lighter hydrogen molecules must have
a greater velocity than the heavier oxygen molecules; otherwise they
cannot have the same kinetic energy (the kinetic energy of a body is
one-half the product of the mass and the square of the velocity). Since
the pressure of a gas depends upon the kinetic energy of the molecules
and upon their number per cubic centimetre, at the same temperature
and pressure equal volumes must contain equal numbers of oxygen and of
hydrogen molecules. As Joule showed in 1851, from the mass of a gas
per cubic centimetre and from its pressure per square centimetre, the
average velocity of the molecules can be calculated. For hydrogen at 0°
C. and atmospheric pressure the average velocity is about 5500 feet per
second; for oxygen under the same conditions it is something over 1300
feet per second.
All these results of the atomic and molecular theory, however, gave
no information about the absolute weight of the individual atoms and
molecules, nor about their magnitude nor the number of molecules in a
cubic centimetre at a given temperature and pressure. As long as such
questions were unsolved there was a suggestion of unreality in the
theory. The suspicion was easily aroused that the theory was merely
a convenient scheme for picturing a series of observations, and that
atoms and molecules were merely creations of the imagination. The
theory would seem more plausible if its supporters could say how large
and how heavy the atoms and molecules were. The molecular theory of
gases showed how to solve these problems which chemistry had been
powerless to solve.
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