The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The radius of a molecule, considered as a sphere, is of the order of
magnitude 0·1 μμ, where μμ means 10⁻⁶ millimetre or 0·001 micron. Even
if a molecule is by no means a rigid sphere, the value given shows that
the molecule is almost unbelievably small, or, in other words, that it
can produce appreciable attraction and repulsion in only a very small
region in space.
The number of molecules in a cubic centimetre of gas at 0° C. and
atmospheric pressure has been calculated with fair accuracy as
approximately 27 × 10¹⁸. From this number and from the weight of a
cubic centimetre of a given gas the weight of one molecule can be
found. One hydrogen molecule weighs about 1·65 × 10⁻²⁴ grams, and
one gram of hydrogen contains about 6 × 10²³ atoms and 3 × 10²³
molecules. The weight of the atoms of the other elements can be found
by multiplying the weight of the hydrogen atom by the relative atomic
weight of the element in question—16 for oxygen, 14 for nitrogen, etc.
If the pressure on the gas is reduced as much as possible (to about one
ten-millionth of an atmosphere) there will still be 3 × 10¹² molecules
in a cubic centimetre, and the average distance between molecules will
be about one micron. The mean free path between two collisions will be
considerable, about two metres, for instance, in the case of hydrogen.
The values found for the number, weight and dimensions of molecules
are either so very large or so extremely small that many people,
instead of having more faith in the atomic and molecular theory,
perhaps may be more than ever inclined to suppose the atoms and
molecules to be mere creations of the imagination. In fact, it is only
two or three decades ago that some physicists and chemists—led by the
celebrated German scientist, Wilhelm Ostwald—denied the existence of
atoms and molecules, and even went so far as to try to remove the
atomic theory from science. When these sceptics, in defence of their
views, said that the atoms and molecules were, and for ever would be,
completely inaccessible to observation, it had to be admitted at that
time that they were seemingly sure of their argument, in this one
objection at any rate.
A series of remarkable discoveries at the close of the nineteenth
century so increased our knowledge of the atoms and improved the
methods of studying them that all doubts about their existence had to
be silenced. However incredible it may sound, we are now in a position
to examine many of the activities of a single atom, and even to
count atoms, one by one, and to photograph the path of an individual
atom. All these discoveries depend upon the behaviour of atoms as
electrically charged, moving under the influence of electrical forces.
This subject will be developed in another section after a discussion of
some phenomena of light, an understanding of which is necessary for the
appreciation of the theory of atomic structure proposed by Niels Bohr.
Public-domain text, read in full here on John Shaqi.
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