The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
Another interesting discovery was soon made, namely, that the sodium
line has exactly the same wave-length as the light lacking in the solar
spectrum, where the double D-line is located. About 1860 Kirchhoff and
Bunsen explained this remarkable coincidence as well as others of the
same nature. They showed by direct experiment that if sodium vapour is
at a high temperature it can not only send out the yellow light, but
also absorb light of the same wave-length when rays from a still warmer
glowing body pass through the vapour. This phenomenon is something like
that in the case of sound waves where a resonator absorbs the pitch
which it can emit itself. The existence of the dark D-line in the solar
spectrum must then mean that in the outer layer of the sun there is
sodium vapour present of lower temperature than the white-hot interior
of the sun, and that the light corresponding to the D-line is absorbed
by the vapour. Several ingenious experiments, which cannot be described
here, have given further evidence in favour of this explanation.
In the other line spectra, just as in that from the common salt flame,
definite lines correspond to definite elements and not to chemical
compounds. The emission of these lines is then not a molecular
characteristic, but an atomic one. The line spectra of metals can often
be produced by vaporizing a metallic salt in a spirit flame or in a
hot, colourless gas flame (from a Bunsen burner). It is even better to
use an electric arc or strong electric sparks. The atoms from which
gaseous molecules are formed can also be made to emit light which by
means of the spectroscope is shown to consist of a line spectrum. These
results are obtained by means of electric discharges of various kinds,
arcs, and spark discharges through tubes where the gas is in a rarefied
state.
The other Fraunhofer lines in the solar spectrum correspond to bright
lines in the line spectra of certain elements which exist here on
earth. These Fraunhofer lines must then be assumed to be caused by the
absorption of light by the elements in question. This may be explained
by the presence of these elements as gases in the solar atmosphere,
through which passes the light from the inner layer. This inner surface
would in itself emit a continuous spectrum.
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