The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The electrically produced electromagnetic waves, as already mentioned,
have wave-lengths much greater than 300 μ. In wireless telegraphy
there are generally used wave-lengths of one kilometre or more,
corresponding to frequencies of 300,000 vibrations per second or less.
By direct electrical methods it has, however, not been possible to
obtain wave-lengths less than about one-half a centimetre, a length
differing considerably from the 0·3 millimetre wave of the longest
infra-red rays. Wave-lengths much less than 0·02 μ or 20 μμ exist in
the so-called _Röntgen rays_ or _X-rays_ with wave-lengths
as small as 0·01 μμ corresponding to a frequency of 30 × 10¹⁸. These
rays cannot possibly be studied even with the finest artificially made
gratings, but crystals, on account of the regular arrangement of the
atoms, give a kind of natural grating of extraordinary fineness. With
the use of crystal gratings success has been attained in decomposing
the Röntgen rays into a kind of spectrum, in measuring the wave-lengths
of the X-rays and in studying the interior structure of the crystals.
The German Laue, the discoverer of the peculiar action of crystals on
X-rays (1912), let the X-rays beams pass through the crystal, obtaining
thereby photographs of the kind illustrated in Fig. 11. Later on
essential progress was due to the Englishmen, W. H. and W. L. Bragg,
who worked out a method of investigation by which beams of X-rays are
reflected from crystal faces. The greatest wave-length which it has
been possible to measure for X-rays is about 1·5 μμ, which is still a
long way from the 20 μμ of the furthermost ultra-violet rays.
It may be said that the spectrum since Fraunhofer has been made not
only longer but also finer, for the accuracy of measuring wave-lengths
has been much increased. It is now possible to determine the
wave-length of a line in the spectrum to about 0·001 μμ or even less,
and to measure extraordinarily small changes in wave-lengths, caused by
different physical influences.
In addition to the continuous spectra emitted by glowing solids
or liquids, and to the line spectra emitted by gases, and to the
absorption spectra with dark lines, there are spectra of still another
kind. These are the absorption spectra which are produced by the
passage of white light through coloured glass or coloured fluids. Here
instead of fine dark lines there are broader dark absorption bands,
the spectrum being limited to the individual bright parts. There are
also the band spectra proper, which, like the line spectra, are purely
emission spectra, given by the light from gases under particular
conditions; these seem to consist of a series of bright bands which
follow each other with a certain regularity (cf. Fig. 12). With
stronger dispersion the bands are shown to consist of groups of bright
lines.
[Illustration:
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