The atom and the Bohr theory of its structure : $b an elementary presentation — John Shaqi
The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
Faraday found that the quantity of hydrogen which in the above
experiment is transferred to the cathode in a given time is
proportional to the quantity of electricity transferred in the same
time. A gram of hydrogen always takes the same amount of electricity
with it. By experiment this amount of electricity can be determined,
and, since the weight in grams of the hydrogen atom is known, it is
possible to calculate the amount of one atom. In electrostatic units
it is 4·77 × 10⁻¹⁰, _i.e._, 477 billionth[1] parts. A chlorine atom
then carries with it 4·77 × 10⁻¹⁰ electrostatic units of negative
electricity. Since its atomic weight is 35·5, then 35·5 grams of
chlorine will take as much electricity as 1 gram of hydrogen. The ratio
_e_/_m_ between the charge _e_ and the mass _m_ is then 35·5 times as
great for hydrogen as for chlorine.
[1] Billion used here to mean one million million, and trillion to mean
one million billion.
We have temporarily restricted ourselves to the electrolysis of
hydrogen chloride. Let us now assume that we have chloride of zinc
(ZnCl₂), which, by electrolysis, is separated into chlorine and zinc.
Each atom of chlorine will, as before, carry 4·77 × 10⁻¹⁰ units of
negative electricity to the anode; but since zinc is divalent (cf. p.
17) and one atom of zinc is joined to two of chlorine, therefore one
atom of zinc must carry a charge of 2 × 4·77 × 10⁻¹⁰ units of positive
electricity to the cathode. An atom or a group of atoms, with valence
of three, in electrolysis carries 3 × 4·77 × 10⁻¹⁰ units, etc.
We see then, that the quantity of electricity which accompanies the
atoms in electrolysis is always 4·77 × 10⁻¹⁰ electrostatic units or an
integral multiple thereof. This suggests the thought that electricity
is atomic and that the quantity 4·77 × 10⁻¹⁰ units is the smallest
amount of electricity which can exist independently, _i.e._, the
_elementary quantum of electricity_ or the “atom of electricity.”
The atom of a monovalent element, when charged or ionized, should
have one atom of electricity; a divalent, two, etc. On the two-fluid
theory it was most reasonable to assume that there were two kinds
of atoms of electricity representing, respectively, positive and
negative electricity. In Fig. 15 there is given, in accordance with the
two-fluid theory, a rough picture of a chlorine ion and a hydrogen ion
and their union into a molecule.
[Illustration: FIG. 15.—Provisional representation (according
to the two-fluid theory) of
A, a hydrogen ion; B, a chlorine ion; and C, a molecule of hydrogen
chloride.]
The atoms of electricity seemed to differ essentially from the
usual atoms of the elements in their apparent inability to live
independently; they seemed to exist only in connection with the atoms
of the elements. They would seem much more real if they could exist
independently. That such existence really is possible, has been
discovered by the study of the motion of electricity in gases.
Vacuum Tube Phenomena.
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