The atom and the Bohr theory of its structure : $b an elementary presentation — John Shaqi
The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
After the atom of negative electricity had been isolated, in the form
of cathode rays, the next suggestion was that corresponding positive
electric particles might be discharged from the anode in a vacuum tube.
By special methods success has been attained in showing and studying
rays of positive particles. In order to separate them from the negative
cathode ray particles the German scientist, Goldstein, let the positive
particles pass through canals in the cathode; they are therefore
called _canal rays_. The velocity of the particles is much less
than that of the cathode rays, and the ratio _e_/_m_ between
charge and mass is much smaller and varies according to the gas in the
tube. In experiments where the tube contains hydrogen, rays are always
found for which _e_/_m_, as in electrolysis, is about ¹/₂₀₀₀
of the ratio in the cathode rays. Therefore there can be scarcely any
doubt that these canal rays are made up of charged hydrogen atoms
or hydrogen ions. The values found with other gases indicate that
the particles are atoms (or molecules sometimes) of the elements in
question, with charges one or more times the elementary quantum of
electricity (4·77 × 10⁻¹⁰ electrostatic units). Research in this field
has also been due in particular to J. J. Thomson. From his results, as
well as from those obtained by other methods, it follows that positive
electricity, unlike negative, cannot appear of its own accord, but is
inextricably connected to the atoms of the elements.
The Nature of Electricity.
The earlier conceptions of a one or two-fluid explanation of the
phenomena of electricity appear now in a new light. We are led to think
of a neutral atom as consisting of one mass charged with positive
electricity together with as many electrons negatively charged as are
sufficient to neutralize the positive. If the atom loses one, two or
three electrons, it becomes positive with a charge of one, two or
three elementary quanta of electricity, or for the sake of simplicity
and brevity we say that the atom has one, two or three “charges.”
If, on the other hand, it takes up one, two or three extra electrons
it has one, two or three negative charges. Fig. 18 can give help
in understanding these ideas, but it must not be thought that the
electrons are arranged in the way indicated. The substances, which
appear as electropositive in electrolysis—_i.e._ hydrogen and
metals—should then be such that their atoms easily lose one or more
electrons, while the electronegative elements should, on the other
hand, easily take up extra electrons. Elements should be monovalent or
divalent according as their atoms are apt to lose or to take up one or
two electrons. From investigations with the vacuum tube it appears,
however, that the atoms of the same element can in this respect behave
in more ways than would be expected from electrolysis or chemical
valence.
[Illustration: FIG. 18.—Provisional representation (according
to the electron theory) of
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