The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
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The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
We shall best understand the meaning of this if we consider the
simplest of the elemental atoms, namely, the atom of hydrogen with its
positive nucleus and its one electron revolving about the nucleus.
How could it be possible to explain from such a simple structure the
many sharp spectral lines given by the Balmer-Ritz formula (p. 57)?
As has previously been mentioned, the classical electron theory seemed
to demand a very complicated atomic structure for the explanation of
these lines. According to the electron theory, the atoms may be likened
to stringed instruments which are capable of emitting a great number
of tones, and in these atoms the electrons are naturally supposed
to correspond to the “strings.” But the hydrogen atom has only one
electron, and it hardly seems credible that in a mass of hydrogen the
individual atoms would be tuned for different “tones,” with definite
frequencies of vibration.
Now, it certainly cannot be concluded from the analogy with the
stringed instrument that a single electron can emit light of only a
single frequency at one time, corresponding to a single spectral line.
For a plucked string will, as we know, give rise to a simple tone only
if it vibrates in a very definite and particularly simple way; in
general it will emit a compound sound which may be conceived as made up
of a “fundamental” and its so-called “overtones,” or “harmonies” whose
frequencies are 2, 3, ... times that of the fundamental (_i.e._
integral multiples of the latter). These overtones may arise even
separately because the string, instead of vibrating as a whole,
may be divided into 2, 3, ... equally long vibrating parts, giving
respectively 2, 3, ... times as great frequencies of vibration. We call
such vibrations “harmonic oscillations.” The simultaneous existence of
these different modes of oscillation of the string may be thought of in
the same way as the simultaneous existence of wave systems of different
wave-lengths on the surface of water. Corresponding to the possibility
of resolving the motion of the string into its “harmonic components,”
the compound sound waves produced by the string can be resolved by
resonators (cf. p. 44) into tones possessing the frequencies of these
components.
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