The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
According to the laws of electrodynamics the situation with the
electron revolving about the hydrogen nucleus might be expected to
be somewhat similar to that described above in connection with the
vibrating string. If the orbit of the electron were a circle, it
should emit into the ether electromagnetic waves of a single definite
wave-length and corresponding frequency, ν, equal to ω, the frequency
of rotation of the electron in its orbit; that is, the number of
revolutions per second. But just as a planet under the attraction
of the sun, varying inversely as the square of the distance, moves
in an ellipse with the sun at one focus, so the electron, under the
attraction of the positive nucleus, which also follows the inverse
square law, will in general be able to move in an ellipse with the
nucleus at one focus. The electromagnetic waves which are emitted
from such a moving electron may on the electron theory be considered
as composed of light waves corresponding to a series of harmonic
oscillations with the frequencies:
ν₁ = ω, ν₂ = 2ω, ν₃ = 3ω ... and so on,
where ω, as before, is the frequency of revolution of the electron.
According as the actual orbit deviates more or less from a circle, the
frequencies ν₂, ν₃ ... will appear stronger or weaker in the compound
light waves emitted. But the actual distribution of spectral lines
in the real hydrogen spectrum presents no likeness whatever to this
distribution of frequencies.
From this it is evident that no agreement can be reached between
the classical electron theory on the one hand and the Rutherford
atom model on the other. Indeed, the disagreement between the two is
really far more fundamental than has just been indicated. According to
Lorentz’s explanation of the emission of light waves, the electrons
in a substance (see again p. 75) should have certain equilibrium
positions, and should oscillate about these when pushed out of them by
some external impulse. The energy which is given to the electron by
such an impulse is expended in the emission of the light waves and is
thus transformed into radiation energy in the emitted light, while the
electrons fall to rest again unless they receive in the meantime a new
impulse. We can get an understanding of what these impulses in various
cases may be by thinking of them, in the case of a glowing solid, for
example, as due to the collisions of the molecules; or in the case of
the glowing gas in a discharge tube, from the collisions of electrons
and ions. The oscillating system represented by the electron (the
“oscillator”) will possess under these circumstances great analogy with
a string which after being set into vibration by a stroke gradually
comes back to rest, while the energy expended in the stroke is emitted
in the form of sound waves. Although the vibrations of the string
become weaker after a while, the period of the vibrations will remain
unchanged; the string vibrations like pendulum oscillations have an
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