The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
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The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
invariable period, and the same will be the case with the frequency
of the electron if the force which pulls it back into its equilibrium
position is directly proportional to the displacement from this
position (the “harmonic motion” force).
Rutherford’s atomic model is, however, a system of a kind wholly
different from the “oscillator” of the electron theory. The one
revolving hydrogen electron will find a position of “rest” or
equilibrium only in the nucleus itself, and if it once becomes united
with the latter it will not easily escape; it will then probably
become a nuclear electron, and such a process would be nothing less
than a transformation of elements (see p. 79). On the other hand,
it follows necessarily from the fundamental laws of electrodynamics
that the revolving electron must emit radiation energy, and, because
of the resultant loss of energy, must gradually shrink its path and
approach nearer the nucleus. But since the nuclear attraction on the
electron is inversely proportional to the square of the distance,
the period of revolution will be gradually decreased and hence the
frequency of revolution ω, and the frequency of the emitted light will
gradually increase. The spectral lines emitted from a great number
of atoms should, accordingly, be distributed evenly from the red end
of the spectrum to the violet, or in other words there should be no
line spectrum at all. It is thus clear that Rutherford’s model was not
only unable to account for the number and distribution of the spectral
lines; but that with the application of the ordinary electrodynamic
laws it was quite impossible to account for the existence even of
spectral lines. Indeed, it had to be admitted that an electrodynamic
system of the kind indicated was mechanically unstable and therefore
an impossible system; and this would apply not merely to the hydrogen
atom, but to all nuclear atoms with positive nuclei and systems of
revolving electrons.
However one looks at the matter, there thus appears to be an
irremediable disagreement between the Rutherford theory of atomic
structure and the fundamental electrodynamic assumptions of Lorentz’s
theory of electrons. As has been emphasized, however, Rutherford
founded his atomic model on such a direct and clear-cut investigation
that any other interpretation of his experiments is hardly possible. If
the result to which he attained could not be reconciled with the theory
of electrodynamics, then, as has been said, this was so much the worse
for the theory.
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