The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
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The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
Naturally, Bohr himself clearly recognized the formal nature of the
agreement between the Balmer-Ritz formula and his postulates. But Bohr
was the first to see that the quantum theory afforded the possibility
of bringing about such an agreement, and he saw, moreover, that the
agreement was not merely fortuitous, but contained within it something
really fundamental, on which one could build further. That atomic
processes on his theory took on an unreasonable character (compared
with the classical theory) was nothing to worry about, for Bohr had
come to the clear recognition that it was completely impossible to
understand from known laws the Planck-Einstein “quantum radiation,”
or to deduce the properties of the spectrum from the Rutherford atom
alone. He therefore saw that his theory was really not introducing new
improbabilities, but was only causing the fundamental nature of the
contradictions which had previously hindered development in this field
to appear in a clearer light.
But in addition to this the choice of the dimensions of the stationary
states was by no means so arbitrary as might appear in the foregoing.
In his first presentation of the theory of the hydrogen spectrum, Bohr
had derived his results from certain considerations connected with the
quantum theory—considerations of a purely formal nature, indeed, just
as those developed in the preceding, but leading to agreement with the
spectral formulæ. He, moreover, called attention to the fact that the
values obtained for the orbital dimensions were of the same order of
magnitude as those which could be expected on wholly different grounds.
The diameter of the innermost orbit, _i.e._, that which defines
the outer limit of the atom in the normal state, was found to be, as
has been noted above, about 10⁻⁸ cm., _i.e._, of the same order
of magnitude as the values obtained for the diameters of molecules
on the kinetic theory of gases (see p. 27). The stationary states
corresponding to very high quantum numbers one could expect to meet
only when hydrogen was very attenuated, for otherwise there could be
no room for the large orbits. We note that the 32nd orbit must have
a diameter 32² (or over 1000 times) as great as the innermost orbit.
Since, now, lines with high number in a hydrogen series correspond on
the Bohr theory to transitions from orbits of high number to an inner
orbit, it became understandable why only comparatively few lines of
the Balmer series are ordinarily observed in the discharge tube, while
many more lines are observed in the spectra of certain stars. For in
such stars the possibility is left open for hydrogen to exist in a
very attenuated state, and yet in such large masses that the lines in
question can become strong enough for observation. In fact, one must
assume that in a great mass of hydrogen a very large number of atoms
send out simultaneously light of the wave-length corresponding to
one line. For the ionizing work, _i.e._, the work necessary to
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