[Illustration: _The latter is also shown aboard a research vessel
(inset) during tests made at sea._]
OXYGEN ANALYZER The amount of dissolved oxygen in any part of the ocean
is a basic quantity that must be determined before some kinds of
research can be undertaken. For example, oxygen concentration is
important in determining the life-support capability of seawater and in
measuring deep-water mixing. In the past this measurement has had to be
determined by laborious chemical methods that may subject the water
sample to contamination by exposure to atmospheric oxygen. Under an AEC
contract, the Research Triangle Institute has developed a dissolved
oxygen analyzer that relies on the quantitative oxidation by dissolved
oxygen of thallium metal containing a known ratio of radioactive
thallium-204.
The seawater sample passes through a column lined with thallium. The
thallium is oxydized and goes into solution. It then passes between two
facing pancake-shaped radiation counters that record the level of beta
radiation from the thallium-204. Since the rate of oxidation, and
therefore the rate of release of the thallium to solution, is
proportional to the amount of dissolved oxygen in the water, it is
simple to calibrate the device to show oxygen content. The system is
sensitive enough to detect one part of oxygen in 10 billion of water.
And, the device can be towed and take readings at depths of up to one
mile, an added advantage that obviates the chances of surface-air
contamination.
NEUTRON ACTIVATION ANALYSIS Nuclear energy is contributing to the more
accurate and more rapid analysis of minerals in the sea in at least two
different ways. The first employs neutron activation analysis, which we
have already mentioned. This method is valuable not only in analyzing
sediments cored from the ocean floor, but also in the detection and
quantitative analysis of trace elements in the water. Knowledge of the
role of all natural constituents in the ocean is essential to an
understanding of the complex interrelationships of the ocean
environment, as we have seen. Identification of trace elements also is a
necessary preliminary to determining the effects of purposely introduced
radionuclides. Collection of the minute quantities of trace elements is
very difficult at best. Once they have been collected and concentrated,
neutron activation analysis provides a means for their identification
and measurement.
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