The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
[Illustration: Nuclear reactor]
This is called a “swimming pool” reactor because the nuclear fuel,
built into metal rods, is held in a framework at the bottom of a deep
pool of water. The water serves as a shield to protect workers from
the radiation and also helps the reactor “go” by slowing down neutrons
to make them more likely to interact with the target atoms. “Swimming
pool” reactors are frequently used for neutron activation analysis and
typically provide neutron fluxes of over 10¹³ (10 million million)
neutrons per square centimeter per second.
[Illustration: Quartz capsules]
These sealed quartz capsules contain samples to be irradiated in a
nuclear reactor. They are about to be placed in the aluminum can,
which will be sealed and positioned at the end of an aluminum pole,
close to the core of a “swimming pool” reactor. Often samples are
placed in plastic tubes and are carried in and out of a reactor by air
pressure in a pneumatic tube system.
You carefully scrape off a small amount of material, weigh it on a
sensitive balance, and put it into a short piece of pure quartz tubing.
You do the same with an ordinary piece of silicon for comparison and
then seal both tubes with an oxygen-gas torch. Although the tubes are
both ¼ inch in diameter and about 1 inch long, the first tube is just
slightly longer so you will be able to determine which is which after
the irradiation.
Off it goes to the reactor in a carefully wrapped package along with
instructions to irradiate the tubes for 12 hours in a neutron flux of
about 10¹³ neutrons per square centimeter per second and to return them
as quickly as possible after they are removed from the reactor.
The following week, the samples are delivered about 4 hours after they
were removed from the reactor. Working quickly but carefully, you note
that they are radioactive but easily handled by ordinary laboratory
techniques. You break the quartz tubes one at a time and attach each of
the two pieces of silicon to a card with self-sticking tape. Then you
place each card, in turn, on a holder close to the gamma-ray detector
for a period of 10 minutes. A spectrum, which is a graph of the quantity
of radiation recorded in each increment of energy over the range
observed for each of the samples, is plotted automatically at the end of
the counting period and you may now compare the compositions of the two
samples. (See the figure on the next two pages.)
Public-domain text, read in full here on John Shaqi.
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