The patient lies down in a padded aluminum box and, only 4 minutes after the irradiation is concluded, a ring of 4 gamma-ray scintillation detectors[10] begin to measure the gamma rays emitted by his body. These detectors, which are each 4 inches thick and 9⅜ inches in diameter, pass over his body from head to foot. This takes 12½ minutes and since the calcium-49 is decaying with a half-life of 8.8 minutes, the detectors are made to scan at a gradually decreasing rate to compensate for the reduced radioactivity during the later parts of the counting period. The figure on the next page shows the gamma-ray spectrum for the patient. Notice the peak corresponding to an energy of 3.1 MeV. Because there are small contributions to this energy peak from other activated products in the body, repeat counts are taken later (after the calcium-49 has decayed) so that these contributions can be measured and subtracted. Twenty minutes after the irradiation period, the radioactivity of the calcium standards is measured by the same instrument. The ratio of the counts from your patient’s body to that of the standards is 0.210; this serves as an index of the calcium content of his body on this day. Because of the care taken to make the analysis repeatable, this index is probably accurate to about 1 or 2%. Your patient’s disease usually results in a decrease of approximately 3% of the calcium in his body per year. Thus, by making the same measurement a year from now, you will be able to tell if your treatment is a success by noting that the calcium level in your patient’s bones has stopped decreasing at a dangerous rate. In a Plastics Plant _The Problem_ You are an analytical chemist working for a company that makes plastic. It is 11:30 a.m. and you have been called by the plant superintendent because some of the plastic coming from the plant has been showing a yellowish-brown discoloration. There seem to be only a few possible reasons for it, but no easy way to tell which one is correct. One possibility is that a copper tank, in which the plastic is prepared, is somehow being corroded by excess acid in the raw material and minute quantities of dissolved copper are discoloring the plastic. You could prove that this is the cause if you could find copper in the plastic, but the plant superintendent wants the answer immediately because a few hours delay in production will jeopardize a valuable contract, and ordinary chemical analysis would take several hours. How can you quickly determine if there is copper present in the plastic? [Illustration: Graph: “Counts per 12.5 minutes/50 KeV channel” _vs_ “Channel no.”] Element Counts Channel no. 2.75 MeV Na-24 5000 10 3.10 MeV Ca-49 3200 16 3.85 MeV Cl-38 500 33 4.0 MeV Ca-49 100 39 (Values estimated from graph)