The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
In the real world, there are often many reasons _why_ this kind of
analysis is used. As in the situations described here, it may be the
only workable method. Sometimes there may be a choice of methods, but
activation analysis is used because it has certain peculiar advantages
or because it happens to be the most convenient. There are other times,
however, when other analytical methods can and should be used. Such
situations arise when the element sought is not easily activated, or
when a satisfactory alternative method exists that is more economical or
more convenient. The points to remember about the use of activation
analysis are that:
1. In many cases, no elaborate sample preparation procedure is
required.
2. For many elements, it is the most sensitive analytical technique
known.
The diversity of _applications_ in which activation analysis is used is
enormous and will probably continue to be. The examples given here
represent only a tiny fraction of circumstances in which the method has
been used. Consider that it has been used successfully:
1. In the microscopic world of biology and medicine;
2. For meteorites arriving from the vast reaches of space;
3. In the production lines of consumer products;
4. For precious samples of moon rocks;
5. In the most “down-to-earth” business of hunting for new mineral
sources;
6. For exploring the causes of Napoleon’s death nearly 150 years
earlier (see photograph on next page). Today, there is virtually no
field of science and technology that is untouched by this method.
The illustrations of _procedures_ used in the situations described in
this booklet are typical of some in use today. There are many other
situations that require still other techniques. One of the most
exciting, which will be used with increasing frequency in the future,
involves the use of computers. It has been shown that data collected by
high-resolution gamma-ray spectrometers can be “fed” directly to a
computer. The computer can be programmed to identify unknown components
and to determine the concentrations of elements of interest to the
analyst. It is entirely possible to include corrections for radioactive
decay, possible interferences from other elements present, and many
other factors. It appears quite likely that the kinds of analyses
described here (as well as others) may someday be accomplished
automatically, with far smaller chances for error and probably more
economically.
[Illustration: Hair sample]
Samples of Napoleon’s hair. Neutron activation analysis of these hairs
revealed that he had been poisoned with arsenic. (He died, however,
not from arsenic poisoning, but from acute mercury intoxication.)
Public-domain text, read in full here on John Shaqi.
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