The Birth-Time of the World and Other Scientific EssaysJoly, John
Science
The Birth-Time of the World and Other Scientific Essays
Joly, John
Science
or calcium sulphate against sodium chloride; keeping the marine
proportions. Again we find that the magnesium and calcium salts
are the most effective, although so much more dilute than the
sodium salt.
There is no visible clue to the explanation of these results. But
we must conclude as most probable that some action is at work in
the sea water and in the salt solutions which clumps or
flocculates the sediment. For only by the gathering of the
particles together in little aggregates can we explain their
rapid fall to the bottom. It is not a question of viscosity
(_i.e._ of resistance to the motion of the particles), for the
salt solutions are rather more viscous than the fresh water.
Still more remarkable is the fact that every dissolved substance
will not bring about the result. Thus if we dissolve sugar in
water we find that, if anything, the silt settles more slowly in
the sugar solution than in fresh water.
Now there is one effect produced by the solution of such salts as
we have dealt with which is not produced by such bodies as sugar.
The water is rendered a conductor of electricity. Long ago
Faraday explained this as due to the presence of free atoms of
the dissolved salt in the solution, carrying electric charges. We
now speak of the salt as "ionised." That is it is partly split up
into ions or free electrified atoms of chlorine, sodium,
magnesium, etc., according to the particular salt in solution.
This fact leads us to think that these electrified
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atoms moving about in the solution may be the cause of the
clumping or flocculation. Such electrified atoms are absent from
the sugar solution: sugar does not become "ionised" when it is
dissolved.
The suspicion that the free electrified atoms play a part in the
phenomenon is strengthened when we recall the remarkable
difference in the action of sodium chloride and magnesium
chloride. In each of the solutions of these substances there are
free chlorine atoms each of which carries a single charge of
negative electricity. As these atoms are alike in both solutions
the different behaviour of the solutions cannot be due to the
chlorine. But the metallic atom is very different in the two
cases. The ionised sodium atom is known to be _monad_ or carries
but _one_ positive charge; whereas the magnesium atom is _diad_ and
carries _two_ positive charges. If, then, we assume that the
metallic, positively electrified atom is in each case
responsible, we have something to go on. It may be now stated
that it has been found by experiment and supported by theory that
the clumping power of an ion rises very rapidly with its valency;
that is with the number of unit charges associated with it. Thus
diads such as magnesium, calcium, barium, etc., are very much
more efficient than monads such as sodium, potassium, etc., and
again, triads such as aluminium are, similarly, very much more
powerful than diad atoms. Here, in short, we have arrived at the
active cause of the phenomenon. Its inner mechanism
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