The Birth-Time of the World and Other Scientific EssaysJoly, John
Science
The Birth-Time of the World and Other Scientific Essays
Joly, John
Science
But when we come to consider inanimate actions in relation to
time, or time-rate of change, we find a new feature in the
phenomena attending transfer of energy; a feature which is really
involved in general statements as to the laws of physical
interactions.[1] It is seen, that the attitude of inanimate
material systems is very generally, if not in all cases,
retardative of change--opposing it by effects generated by the
primary action, which may be called "secondary" for convenience.
Further, it will be seen that these secondary effects are those
concerned in bringing about the inevitable dissipation.
As example, let us endeavour to transfer gravitational potential
energy contained in a mass raised above the surface of the Earth
into an elastic body, which we can put into compression by
resting the weight upon it. In this way work is done against
elastic force and stored as elastic potential energy. We may deal
with a metal spring, or with a mass of gas contained in a
cylinder fitted with a piston upon which the weight may be
placed. In either case we find the effect of compression is to
raise the temperature of the substance, thus causing its
[1] Helmholtz, _Ice and Glaciers._ Atkinson's collection of his
Popular Lectures. First Series, p.120. Quoted by Tate, _Heat_,
p. 311.
63
expansion or increased resistance to the descent of the weight.
And this resistance continues, with diminishing intensity, till
all the heat generated is dissipated into the surrounding medium.
The secondary effect thus delays the final transfer of energy.
Again, if we suppose the gas in the cylinder replaced by a vapour
in a state of saturation, the effect of increased pressure, as of
a weight placed upon the piston, is to reduce the vapour to a
liquid, thereby bringing about a great diminution of volume and
proportional loss of gravitational potential by the weight. But
this change will by no means be brought about instantaneously.
When a little of the vapour is condensed, this portion parts with
latent heat of vaporisation, increasing the tension of the
remainder, or raising its point of saturation, so that before the
weight descends any further, this heat has to escape from the
cylinder.
Many more such cases might be cited. The heating of india-rubber
when expanded, its cooling when compressed, is a remarkable one;
for at first sight it appears as if this must render it
exceptional to the general law, most substances exhibiting the
opposite thermal effects when stressed. However, here, too, the
action of the stress is opposed by the secondary effects
developed in the substance; for it is found that this substance
contracts when heated, expands when cooled. Again, ice being a
substance which contracts in melting, the effect of pressure is
to facilitate melting, lowering its freezing point. But
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