+53. Duclaux theory.+--Duclaux (1884) and Loevenhart (1904) and others
do not accept Hammarsten's theory; but to most workers it seems
probable, at least, that the action of the rennin is to cause a cleavage
of casein with formation of paracasein. However, the chemical and
physical differences observed between casein and paracasein appear to be
so slight that Loevenhart and some others think that they are only
physical, perhaps differences in the size of the colloid or solution
aggregates. Loevenhart conceives of a large part of the work of the
rennet (or of the acid, in acid and heat coagulation) as being a freeing
of the calcium to make it available for precipitation. Some think that
the aggregates of paracasein are larger than those of casein, but there
is more evidence of their being smaller, which idea corresponds with the
findings of Bosworth, though he looks on the change as a true cleavage.
+54. Bang's theory.+--Another description of the precipitation is given
by Bang (1911), who studied the progress of the coagulation process by
means of interruptions at definite intervals. His observations confirm
the idea that rennin causes the formation of paracasein, and that the
calcium salt serves only for the precipitation of the paracasein; the
rennin has to do also with the mobilizing of lime salts. According to
Bang, before coagulation occurs, paracaseins with constantly greater
affinity for calcium phosphate are produced. These take up increasing
amounts of calcium phosphate, until finally the combination formed can
no longer remain in solution.
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