The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
History
The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
Footwear industry; Gutta-percha; Rubber; Tanning
Yet another discovery was necessary in order to fully complete the
magnificent results which Hayward had developed. Sulphurized goods were
found to emit a very unpleasant odor, and what was of still greater
importance, the goods became rigid in cold weather, and loose and
elastic in warm weather. These objections must be removed, or the
discoveries of Hayward would lose their chief importance. Vulcanization,
subsequently discovered by Goodyear, was the important element to be
applied. To Hayward and Goodyear conjointly is the world indebted for
the benefits which have followed as a sequence to their discoveries.
They stand like the Siamese twins connected by reciprocal inventive
faculties, the one equally dependent upon the other for the success
which has crowned their united efforts. The intelligent reader cannot
fail to see the relative importance which the one holds to the other,
and how admirably the genius of Goodyear completed what the untiring
energy of Hayward first disclosed. This much is necessary at this point
to introduce the reader to what follows concerning vulcanization.
On the 24th day of February, 1839, Mr. Hayward secured a patent for
vulcanizing India-rubber by means of sulphur, which patent was assigned
to Charles Goodyear—a man of shrewd and future grasping mind. Some idea
of the importance of this improvement may be formed from the fact that
it has been a subject of continual litigation for a number of years;
yea, almost since the day the patent was issued. It is the real
vulcanizing substance now used in the manufacture of India-rubber
fabrics of every description. The claim is in these words: “the
combining of sulphur with gum-elastic, whether in solution or in
substance, either by mixing with the digested India-rubber, kneading it,
or sprinkling it on the surface of sheets and pressing it in.”
At the time of the famous contest between Goodyear and Day, testimony
was produced by which it was endeavored to be proved that the
vulcanization of India-rubber was discovered in Germany by F.
Luedersdorff, six years before Hayward’s patent was granted. Some doubts
have been expressed concerning the statement. Whether true or false, we
cannot see why the circumstance should detract in the least from the
claims or position of Mr. Hayward, inasmuch as it is very conclusive
that his discovery was purely accidental.
A Prussian pamphlet published at Berlin in 1832, describes the
experiments made by F. Luedersdorff with India-rubber, and the
production of sulphurized India-rubber compounds. The Scientific
American in speaking upon this subject, and combating the claims of the
learned Prussian has the following:—
Public-domain text, read in full here on John Shaqi.
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