The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
History
The Boot and Shoe Manufacturers' Assistant and Guide.: Containing a Brief History of the Trade. History of India-rubber and Gutta-percha, and Their Application to the Manufacture of Boots and Shoes. Full Instructions in the Art, With Diagrams and Scales, Etc., Etc. Vulcanization and Sulphurization, English and American Patents. With an Elaborate Treatise on Tanning.
Footwear industry; Gutta-percha; Rubber; Tanning
“The clamminess of dissolved India-rubber, and its tendency to
decomposition are attributed to its resinous properties. On page 28, the
following language occurs: ‘After a long series of experiments, in which
neither deodorizing or oxidizing substances, neither alkalies, nor
mechanical means, which affected the speedy drying, produced the desired
result; I succeeded at last in finding in sulphur the substance, which
even in very small quantities, perfectly prevented the injurious effect
of the resinous aggregation.’ Instructions are given how to prepare the
sulphur solution, by heating and stirring three parts of flour sulphur
in one hundred parts of rectified oil of turpentine, bringing them to a
boiling heat, then dissolving the India-rubber in the solution. By
Hayward’s patent, one teaspoonful of sulphur was mixed with that
quantity of oil of turpentine required to dissolve a pound of
India-rubber, and in this respect, there is little difference between
his method and that of the Prussian doctor. It is the sulphur which is
the grand agent in the production of vulcanized India-rubber, no matter
how combined, in solution, or with India-rubber softened by heat. Leave
sulphur out of the question, and we would have no vulcanized
India-rubber fabrics.
“The question now arises, what reliance is there to be placed upon the
authenticity of this pamphlet, published six years before Hayward’s
patent was obtained? We have been assured that the original work is in
the College Library, at Providence, R. I.; but it is rather singular,
that in the many controversies on this subject, and the numerous suits
at law which have taken place, respecting the originality of the
invention, that such information was not produced as testimony before
some tribunal.
“That Dr. Luedersdorff made the experiments described, we will assume to
be true in every respect, but neither is our country or any other
indebted to him in the least, for the introduction and success of
India-rubber manufactures. To American inventors alone, is the world
indebted for the invention of vulcanized India-rubber. Hayward was no
doubt totally ignorant of the Prussian doctor’s experiments; he probably
could not read German; he made the discovery of sulphurized India-rubber
by his own efforts, and he is an original inventor, in this sense of the
term.”
We have thus given a brief account of this remarkable discovery.
Heretofore but little has been written or published upon the discovery,
and the subsequent inventions to which it gave rise. The books which
have been published have carefully avoided full and complete statements
or facts, and have contained little or no information of value, but on
the contrary, have seemed, at least, to deal in generalities calculated
to befog and mislead.
Public-domain text, read in full here on John Shaqi.
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