The Boy's Book of Industrial Information — John Shaqi
The Boy's Book of Industrial InformationNoyce, Elisha
General
The Boy's Book of Industrial Information
Noyce, Elisha
Industrial arts -- Juvenile literature; Technology -- Juvenile literature
This beautiful blue color is made by mixing solutions of sulphate
of iron (green vitriol) and prussiate of potash together, when the
Prussian blue falls in the form of a precipitate, or moist powder,
of a pale greenish color, but which, by exposure to the air and
the addition of a little nitric acid, becomes intensely blue; but
the Prussian blue of commerce is never pure, for the solution of
prussiate of potash is used as it comes from the factory, before
being crystallized, and contains carbonate of potash, to get rid
of which, alum is added, and the result is, the formation of a
considerable amount of alumina, which is a white earth produced from
the alum, and which falls down in the precipitate mixed with the
Prussian blue, which is thereby increased in bulk and but little
injured in color; when a larger quantity of this alumina is purposely
produced, the result is a blue of a rather less intense color,
called “Antwerp blue.” The chemical name for pure Prussian blue is
percyanide of iron. Chinese blue is this substance in its purest
state.
PRUSSIATE OF POTASH.
Prussiate of potash is the commercial name given to what chemists
call “ferrocyanide of potassium,” it is used largely for the
production of Prussian blue, and also in the art of electro-plating,
which, of late, has greatly increased the demand for its manufacture,
and many patents have been taken out for various modifications in the
form of production, the result, however, is the same, and it occurs
in commerce in magnificent crystals of a square form, with bevelled
edges, and of a yellow color; there is, however, another kind called
the “red prussiate,” which is much used in the process of calico
printing. Prussiate of potash is made by heating together carbonate
of potash, scraps of iron, and any kind of animal refuse, as blood,
horns and hoofs, clippings of skin or old woollen rags; these are
stirred together, and the heat raised, till they form a sort of paste
of a black color, which, when cold, is thrown into water and all the
soluble parts washed out; this fluid is filtered till quite clear,
evaporated, and set aside that crystals may form; these are dissolved
and again crystallized. The red prussiate is made by passing chlorine
over the yellow prussiate in powder dissolving and crystallizing.
The most deadly of all poisons, prussic or hydrocyanic acid, is
obtained from the ferrocyanide of potassium, or prussiate of potash,
by adding diluted sulphuric acid and distilling the vapour into an
ice-cold receiver. This experiment should never be made by any but
those well conversant with such matters.
SULPHATE OF IRON.
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