The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Dutch bleachers for nine months; and if the spring and summer happened
to be favourable, the operation was well conducted; on the other hand,
if cold and wet, the goods might be more or less injured by continual
exposure to unfavourable atmospheric changes. At the present time, as
much bleaching can be done in nine weeks as might formerly have been
conducted in the same number of months; and the whole of the process of
chlorine bleaching is carried on independent of external atmospheric
caprices, whilst the money paid for the process no longer passes to
Holland, but remains in the hands of our own diligent bleachers and
manufacturers.
_First Experiment._
[Illustration: Fig. 130. A. Flask containing the fuming hydrochloric
acid, which is gently boiled by the heat of the spirit lamp. B. Tube
passing to the Wolfe's bottle, containing pumice-stone or asbestos
moistened with sulphuric acid. C. Second tube passing into a dry empty
bottle, which receives the hydrochloric acid gas.]
As Scheele first indicated, chlorine is obtained by the action of the
black oxide of manganese, on "the Spirit of Salt," or hydrochloric acid;
and the most elementary and instructive experiment showing its
preparation can be made in the following manner:--
[Page 130]
Place in a clear Florence oil-flask, to which a cork and bent tube have
been first fitted, some strong fuming hydrochloric acid. Arrange the
flask on a ring-stand, and then pass the bent tube either to a Wolfe's
bottle containing some pumice-stone moistened with oil of vitriol, or to
a glass tube containing either pumice or asbestos wetted with the same
acid. Another glass tube, bent at right angles, passes away from the
Wolfe's bottle into a receiving bottle. (Fig. 130). On the application
of heat, the hydrochloric gas is driven off from its solution in water,
and any aqueous vapour carried up is retained by the asbestos or pumice
stone wetted with oil of vitriol; the application of the latter is
called _drying the gas_--i.e., depriving it of all moisture; sometimes
the salt called chloride of calcium is used for the same purpose, and it
must be understood by the juvenile chemist that gases are not dried like
towels, by exposure to heat, or _by putting them in bladders before the
fire_, as we once heard was actually recommended, but by causing the gas
charged with invisible steam to pass over some substance having a great
affinity for water. The dry hydrochloric gas falls into the bottle, and
displaces the air, being about one-fourth heavier than the latter, and
gradually overflowing from the mouth of the vessel, produces a white
smoke, which is found to be acid by litmus paper, but has no power to
bleach, and is not green; it is, in fact, a combination of one combining
proportion of chlorine with one of hydrogen, and to detach the latter,
and set the chlorine free, it is necessary to convey the hydrochloric
gas to some body which has an affinity for hydrogen. Such a substance is
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