The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
provided in the use of the black oxide of manganese, which is placed
either in a small flask or in a tube provided with two bulbs, and when
heated with the lamp it separates the hydrogen from the hydrochloric
gas, and forms water, which partly condenses in the second bulb. And now
the gas that escapes is no longer acid and fuming with a white smoke on
contact with the air; but is green, has a strong odour, bleaches, and is
so powerful in its action on all living tissues, that it must be
carefully avoided and not inhaled; if a small quantity is accidentally
inhaled, it produces a violent fit of coughing, which lasts a [Page
131] considerable time, and is only abated by inhaling the diluted
vapour of ammonia, or ether, or alcohol, and swallowing milk and other
softening drinks. (Fig. 131.)
[Illustration: Fig. 131. A. The flask containing the fuming hydrochloric
acid, heated by spirit lamp. B. Tube passing to Wolfe's bottle,
containing the pumice-stone or asbestos wetted with oil of vitriol. C.
Second tube, which passes into a wide-mouthed small flask containing
black oxide of manganese, partly in powder and partly in lump; and the
third tube conveys the chlorine to any convenient vessel. The double
bulb tube, E E, may be substituted for the flask, the oxide of manganese
being contained in the bulb M.--N.B. Any tube may be joined on to
another by a bit of india-rubber tubing, which is tied by string.]
[Illustration: Tube A is joined to tube B by the caoutchouc pipe C, tied
with packthread.]
_Second Experiment._
The mode of preparing chlorine, as already given, though very
instructive, is troublesome to perform; a more simple process may
therefore be described:--
Pour some strong hydrochloric acid upon powdered black oxide of
manganese contained in a Florence oil-flask, taking care that the whole
of the black powder is wetted with the acid so that none of it clings to
the bottom of the flask in the dry state to cause the glass to crack on
the application of heat. A cork and bent glass tube is now attached, and
conveyed to the pneumatic trough; on the application of heat to the
mixture in the flask the chlorine is evolved, and may be collected in
stoppered bottles, the first portion that escapes, although it contains
atmospheric air, should be carefully collected in order to prevent any
[Page 132] accident from inhaling the gas, and it will do very well to
illustrate the bleaching power of the gas, and therefore need not be
wasted. The above process may be described in symbols, all of which are
easily deciphered by reference to the table of elements, page 86.
MnO_{2} + 2 HCl = MnCl + 2HO + Cl.
_Third Experiment._
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