The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Some Dutch metal, or powdered antimony, or a bit of phosphorus,
immediately takes fire when introduced into a bottle containing chlorine
gas, forming a series of compounds termed chlorides, and demonstrating
by the evolution of heat and light, the energetic character of chlorine,
and that oxygen is not the only supporter of combustion; chlorine gas
has even, in some cases, greater chemical power, because some time
elapses before phosphorus will ignite in oxygen gas, whilst it takes
fire directly when placed in a bottle of chlorine.
_Sixth Experiment._
The weight and bleaching power of chlorine are well shown by placing a
solution of indigo in a tall cylindrical glass, leaving a space at the
top of about five inches in depth. By inverting a bottle of chlorine
over the mouth of the cylindrical glass, it pours out like water, being
about two and a half times heavier than atmospheric air, and then, after
placing a ground glass plate over the top of the glass, the chlorine is
recognised by its colour, whilst the bleaching power is demonstrated
immediately the gas is shaken with the indigo solution.
_Seventh Experiment._
As a good contrast to the last experiment, another cylindrical jar of
the same size may be provided, containing a solution of iodide of
potassium with some starch, obtained by boiling a teaspoonful of
arrowroot with some water; any chlorine left in the bottle (sixth
experiment) may be inverted into the top of this glass and shaken, when
it turns a beautiful purple blue in consequence of the liberation of
iodine by the chlorine, whose greater affinity for the base produces
this result. The colour is caused by the union of the iodine and the
starch, which form together a beautiful purple compound, and thus the
apparent anomaly of destroying and producing colour with the same agent
is explained.
[Page 134]
_Eighth Experiment._
Dry chlorine does not bleach, and this fact is easily proved by taking a
perfectly dry bottle, and putting into it two or three ounces of fused
chloride of calcium broken in small lumps, then if a bottle full of
chlorine is inverted over the one containing the chloride of calcium,
taking the precaution to arrange a few folds of blotting paper with a
hole in the centre on the top of the latter to catch any water that may
run out of the chlorine bottle at the moment it is inverted, the gas
will be dried by contact with the chloride of calcium, and if a piece of
paper, with the word chlorine written on it with indigo, and previously
made hot and dry, is placed in the chlorine, no change occurs, but
directly the paper is removed, dipped in water, and placed in a bottle
of damp chlorine, the colour immediately disappears. (Fig. 133.)
[Illustration: Fig. 133. A A. Dry bottle, containing chloride of
calcium. B. Bottle of chlorine. The arrow indicates the gas. C C. The
blotting-paper, to catch any water from the bottle, B. D. The bottle
closed, and containing the paper.]
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