[Illustration: Fig. 187. A. Single cell apparatus with proper vessel, porous tube, and binding screws. B. A large trough divided by a diaphragm of biscuit-ware or very thin porous wood.] _Tenth Experiment._ [Illustration: Fig. 188. A. A single cell, Daniell's, attached to B, the trough containing the mould and the plate of copper. Below is a Smee's battery ready to be attached to a larger trough for the purpose of electrotyping a great number of moulds at the same time.] A single cell apparatus is only adapted to produce small electrotypes, but when larger ones are required, a separate battery of three or four [Page 202] Daniell's or Smee's cells is required; and it is usual to place the mould to be copied in a separate wooden trough, attaching it to the cathode wire, whilst a copper plate is connected with the anode, so that as the solution of sulphate of copper undergoes decomposition by the passage of the electricity, it is kept almost in a normal state, in consequence of the oxygen of the water and the acid passing to the copper plate, which they attack and dissolve as fast as the oxide of copper and hydrogen are liberated at the cathode, where the latter deoxidizes the oxide of copper, and by a secondary action deposits metallic copper; the object being to dissolve fresh metal as the copper is deposited on the mould. (Fig. 188.) _Eleventh Experiment._ To silver electrotypes or other brass and copper articles, the first attention must be paid to the cleanness of them; and when an electrotype is just removed from the copper solution, and washed in clean water, it is at once ready to receive the coating of silver; otherwise, if it has been handled, or is slightly greasy, it should be first boiled in a solution of common washing soda, and then the oxide removed by passing it rapidly in and out of some "Dipping Acid," which is prepared by mixing together equal parts of oil of vitriol and nitric acid; when removed from the "Dipping Acid," it must be well washed in water, and may remain under the surface of the water until the silvering solution is ready. A silver solution may be prepared by dissolving a sixpence in some nitric acid contained in a flask; it is then poured into a solution of common salt, which precipitates the chloride of silver, and leaves the copper in solution--the latter is poured off when the chloride has subsided, and after being well washed in some boiling water, is dissolved in a solution of cyanide of potassium. If a clean electrotype is plunged into this solution, it is immediately covered with a very thin coating of silver, which of course would soon wear off, and in order to increase the thickness of the silver deposit, a single cell arrangement may be constructed of a large gallipot containing a wide porous cell and a circle of amalgamated zinc around it; the arrangement is set in action by pouring a solution of salt (or, still better, sal ammoniac) into and around the porous vessel, and the silvering solution