The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
into the latter; a connecting wire passes from the zinc, and the article
being attached to it, is now plunged into the porous cell, when a
current of electricity slowly passes and deposits the silver on the
copper article. (Fig. 189.)
[Illustration: Fig. 189. The gallipot containing the solution of sal
ammoniac, with the circular amalgamated zinc with wire and binding screw
to which the medal is attached, and contained in the porous vessel
holding the silvering solution and medal.]
[Page 203]
_Twelfth Experiment._
Separate batteries and large troughs containing a solution of cyanide of
silver in cyanide of potassium are used on a grand scale in the
electro-plating establishment of Messrs. Elkington of Birmingham, where
the finest specimens of the art are to be obtained; a plate of silver
being attached to the anode to supply the loss of silver in these
troughs.
_Thirteenth Experiment._
The art of gilding by the agency of electricity is quite as simple as
the processes already described, although greater care is necessary to
avoid any loss of the precious metal. A small bit of gold is dissolved
in a mixture of three parts muriatic acid and one of nitric acid, which
forms the chloride of gold. This is then digested with an excess of
calcined magnesia, and the gold is precipitated as an oxide of the
metal; the latter is collected and washed, and then boiled in strong
nitric acid to remove the magnesia clinging to it, and being again
thoroughly washed with water, is dissolved in a solution of cyanide of
potassium, forming a solution of cyanide of gold and potassium, which
may be placed in the porous cell of the single cell arrangement already
described in the Eleventh Experiment.
_Fourteenth Experiment._
The safest and surest mode of making a gilding solution is to dissolve
some cyanide of potassium in water in a gallipot, and having placed a
porous vessel therein containing the same solution, put a plate of
copper into the porous cell, and some thin foil of pure gold into the
gallipot; connect the gold with the anode of a single cell of Daniell,
and the copper in the porous cell with the cathode, and in a few hours
sufficient gold will be dissolved for the purpose of gilding.
It is usually recommended to warm the gilding solution till it reaches a
temperature of about 150° Fahr., and a very moderate battery power is
employed in Electro Gilding. Indeed the same arrangement, shown in the
Eleventh Experiment, Fig. 189, will also answer for the gilding
solution. After being gilt, the articles may be rubbed with a little
tripoli, or burnished (with taste) by the handle of a key.
_Fifteenth Experiment._
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