The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
If some of the salt called chloride of calcium in the dry and amorphous
state is exposed to the air, it soon absorbs water, or what is termed
_deliquesces_: the same thing occurs with the crystals of carbonate of
potash, and if four ounces are weighed out in an evaporating dish, and
then exposed for about half an hour to the air, a very perceptible
increase in weight is observed by the assistance of the scales and grain
weights. _Deliquescence_ is a term from the Latin _deliqueo_, to melt,
and is in fact a gradual melting, caused by the absorption of water from
the atmosphere. The reverse of this is illustrated with various
crystals, such as Glauber's salt (sulphate of soda), or common washing
soda (carbonate of soda); if a fine clear crystal is taken out of the
solution, called the mother liquor, in which it has been crystallized,
wiped dry, and placed under a glass shade, this salt may remain for a
long period [Page 77] without change, but if it receive one scratch
from a pin, the door is opened apparently for the escape of the water
which it contains, chemically united with the salt, and called water of
crystallization; the white crystal gradually swells out, the little
_quasi_ sore from the pin-scratch spreads over the whole, which becomes
opaque, and crumbling down falls into a shapeless mass of white dust;
this change is called _efflorescence_, from _effloresco_, to blow as a
flower--caused by the abstraction from them of chemically-combined water
by the atmosphere. With reference to the preservation of crystals,
Professor Griffiths recommends them to be oiled and wiped, and placed
under a glass shade, if of a deliquescent nature; or if efflorescent,
they are perfectly preserved by placing them under a glass shade with a
little water in a cup to keep the air charged with moisture and prevent
any drying up of the crystal.
Deliquescent crystals may be preserved by placing them, when dry, in
naphtha, or any liquor in which they are perfectly insoluble. Some
salts, like Glauber's salts, contain so much water of crystallization
that when subjected to heat they melt and dissolve in it, and this
liquefaction of the solid crystal is called "watery fusion." Other
salts, such as bay salt, chlorate of potash, &c., when heated, fly to
pieces, with a sharp crackling noise, which is due sometimes, to the
unequal expansion of the crystalline surface, or the sudden conversion
of the water (retained in the crystal by capillary attraction) into
steam; thus nitre behaves in this manner, and frequently retains water
in capillary fissures, although it is an anhydrous salt, or salt
perfectly free from combined water. The crackling sound is called
_decrepitation_, and is well illustrated by throwing a handful of bay
salt on a clear fire; but this property is destroyed by powdering the
crystals.
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