The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Many substances when melted and slowly cooled concrete into the most
perfect crystals; in these cases heat alone, the antagonist to cohesion,
is the solvent power. Thus, if bismuth be melted in a crucible, and when
cooling, and just as the pellicle (from _pellis_, a skin or crust) is
forming on the surface, if two small holes are instantly made by a rod
of iron and the liquid metal poured out from the inside (one of the
holes being the entrance for the air, the other the exit for the metal);
on carefully breaking the crucible, the bismuth is found to be
crystallized in the most lovely cubes. Sulphur, again, may be
crystallized in prismatic crystals by pursuing a similar plan; and the
great blocks of spermaceti exhibited by wax chandlers in their windows,
are crystallized in the interior and prepared on the same principle.
There are other modes of conferring the crystalline state upon
substances--viz., by elevating them into a state of vapour by the
process called sublimation (from _sublimis_, high or exalted), the
lifting up and condensation of the vapour in the upper part of a vessel;
a process perfectly distinct from that of _distillation_, which means to
separate drop by drop. Both of these processes are very ancient, and
were invented by the Arabian alchemists long antecedent to the seventh
century. Examples of sublimation are shown by heating iodine, and
especially [Page 78] benzoic acid; with the latter, a very elegant
imitation of snow is produced, by receiving the vapour, on some sprigs
of holly or other evergreen, or imitation paper snowdrops and crocuses,
placed in a tasteful manner under a glass vessel. The benzoic acid
should first be sublimed over the sprigs or artificial flowers in a gas
jar, which may be removed when the whole is cold, and a clear glass
shade substituted for it. (Fig. 89.)
All electro deposits on metals are more or less crystalline; and copper
or silver may be deposited in a crystalline form by placing a scraped
stick of phosphorus in a solution of sulphate of copper or of nitrate of
silver. The phosphorus takes away the oxygen from the metal, or
deoxidizes the solution, and the copper or silver reappears in the
metallic form. The surface of the phosphorus must not be scraped in the
air, but under water, when the operation is perfectly safe.
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