The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
It might be expected that these gases would arrange themselves in our
atmosphere in the above order, and if that were the case, we should have
the carbonic-acid _gas_ (a most poisonous one) at the bottom, and
touching the earth, then the oxygen, and, last of all, the nitrogen;
[Page 6] a state of things in which _organized_ life could not exist.
The gases do not, however, separate: indeed, they seem to act as it were
like _vacuums_ to one another, and "the diffusion of gases" has become a
recognised fact, governed by fixed laws. This fact is curiously
illustrated, as shown in our cut, by filling a bottle with carbonic
acid, and another with hydrogen; and having previously fitted corks to
the bottles, perforated so as to admit a tube, place the bottle
containing the carbonic acid on the table, then take the other full of
hydrogen, keeping the mouth downwards, and fit in the cork and tube:
place this finally into the cork of the carbonic-acid bottle, which may
be a little larger than the other, in order to make the arrangement
stand firmer; and after leaving them for an hour or so, the carbonic
acid, which is twenty-two times heavier than the hydrogen, will ascend
to the latter, whilst the hydrogen will descend to the carbonic acid.
The presence of the carbonic acid in the hydrogen bottle is easily
proved by pouring in a wine-glassful of clear lime-water, which speedily
becomes milky, owing to the production of carbonate of lime; whilst the
proof of the hydrogen being present in the carbonic acid is established
by absorbing the latter with a little cream of lime--_i.e._, slacked
lime mixed to the consistence of cream with some water--and setting fire
to the hydrogen that remains, which burns quietly with a yellowish flame
if unmixed with air; but if air be admitted to the bottle, the mixture
of air and hydrogen inflames rapidly, and with some noise. One of the
most elegant modes of showing the diffusion of gases is by taking a
large round dry porous cell, such as would be employed in a voltaic
battery, and having cemented a brass cap with a glass tube attached to
its open extremity, it may then be supported by a small tripod of iron
[Page 7] wire, and the end of the glass tube placed in a tumbler
containing a small quantity of water coloured blue with sulphate of
indigo. If a tolerably large jar containing hydrogen is now placed over
the porous cell, bubbles of gas make their escape at the end of the
tube, because the hydrogen diffuses itself more rapidly into the porous
cell than the air which it already contains passes out. When the jar is
removed, the reverse occurs, hydrogen diffuses out of the porous cell,
and the blue liquid rises in the tube.
This diffusive force prevents the accumulation of the various noxious
gases on the earth, and spreads them rapidly through the great bulk of
the atmosphere surrounding the globe.
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