The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
A singular and almost instantaneous crystallization can be produced by
saturating boiling water with Glauber's salt, of which one ounce and a
half of water will usually dissolve about two ounces; having done this,
pour the solution, whilst boiling hot, into clean oil flasks, or vials
of any kind, previously warmed in the oven, and immediately cork them,
or tie strips of wetted bladder, over the orifices of the flasks or
vials, or pour into the neck a small quantity of olive oil, or close the
neck with a cork through which a thermometer tube has been passed. When
cold, no crystallization occurs until atmospheric air is admitted; and
it was formerly believed that the pressure of the air effected this
object, until some one thought of the oil, and now the theory is
modified, and crystallization is supposed to occur in consequence of the
water dissolving some air which causes the deposit of a minute crystal,
and this being the turning point, the whole becomes solid. However the
fact may be explained, it is certain that when the liquid refuses to
crystallize on the admission of air, the solidification occurs directly
a minute crystal of sulphate of soda, or Glauber's salt, is dropped into
the vessel.
When the crystallization is accomplished, the whole mass is usually so
completely solidified, that on inverting the vessel, not a drop of
liquid falls out.
[Illustration: Fig. 89. A. Gas-jar, with stopper open at first, to be
shut when the lamp is withdrawn. B. Wooden stand, with hole to carry the
cup C, containing the benzoic acid, heated below by the spirit-lamp, S.
F. Flowers or sprigs arranged on pieces of rock or mineral.]
[Page 79]
It may be observed that the same mass of salt will answer any number of
times the same purpose. All that is necessary to be done, is to place
the vial or flask, in a saucepan of warm water, and gradually raise it
to the boiling point till the salt is completely liquefied, when the
vessel must be corked and secured from the air as before. When the
solidification is produced much heat is generated, which is rendered
apparent by means of a thermometer, or by the insertion of a copper wire
into the pasty mass of crystal in the flask, and then touching an
extremely thin shaving or cutting of phosphorus, dried and placed on
cotton wool. Solidification in all cases produces heat. Liquefaction
produces cold.
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