The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
There are other solid oxygenized bodies in which the affinities are less
powerful, and hence a lower degree of heat suffices to liberate the
oxygen gas, and one of the most useful in this respect is the salt
termed chlorate of potash. If the substance is heated by itself, the
temperature required to expel the oxygen is almost as high as that
demanded for the black oxide of manganese; but, strange to say, if the
two substances are reduced to powder, and mixed in equal quantities by
weight, then a very moderate increase of heat is sufficient to cause the
chlorate of [Page 90] potash to give up its oxygen, whilst the oxide of
manganese undergoes no change whatever. It seems to fulfil only a
mechanical office--possibly that of separating each particle of chlorate
of potash from the other, so that the heat attacks the substance in
detail, just as a solid square of infantry might repel almost any
attack, whilst the same body dispersed over a large space might be of
little use; so with the chlorate of potash, which undergoes rapid
decomposition when mixed with and divided amongst the particles of the
oxide of manganese; less so with the red oxide of iron, and still less
with sand or brick-dust. (Fig. 95.)
[Illustration: Fig. 95. Preparation of oxygen from chlorate of potash
and oxide of manganese.
KO.ClO_{5} = { O_{6}
{ KCl.
]
This curious fact is explained usually by reference to what is called
catalytic action, or _decomposition by contact_ ([Greek: _kata_],
downwards, and [Greek: _luô_], I unloosen), _being a power possessed by a
body of resolving another into a new compound without undergoing any
change itself_. To make this term still clearer, we may notice another
example in linen rags, which may be exposed for any length of time to
the action of water without fear of conversion into sugar; if, however,
oil of vitriol is first added to the linen rags, and they are
subsequently digested at a proper temperature with water, then the rags
are converted into sugar (the author has seen a specimen made of an "old
shirt"); but, curious to relate, the oil of vitriol is unchanged in the
process, and if the process be commenced with a pound of acid, the same
quantity is discoverable at the end of the chemical decomposition of the
linen rags, and their conversion into sugar.
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