The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Messrs. Matheson, of Torrington-street, Russell-square, prepare in the
form of wire some of the rarest metals, such as magnesium, lithium, &c.
A wire of the metal magnesium burns magnificently in oxygen gas, and
forms the alkaline earth magnesia. The metal lithium, to which such a
very low combining proportion belongs--viz., 6.5, can also be procured
in the state of wire, and burns in oxygen gas with an intense white
light into the alkaline lithia, which dissolved in alcohol with a little
acetic acid, and burnt, affords a red flame, making a curious contrast
between the effects of colour produced by the metallic and oxidized
state of lithium.
THE ALLOTROPIC CONDITION OF OXYGEN GAS.
The term allotropy (from [Greek: _allotropos_], of a different nature)
was first used by the renowned chemist Berzelius. Dimorphism, or
diversity in crystalline form, is therefore a special case of allotropy,
and is most amusingly illustrated with the iodide of mercury (HgI),
which is made either by rubbing together equal combining proportions
[Page 100]of mercury and iodine (both of which are to be found in the
Table of Elements, page 86), or by carefully precipitating a solution of
corrosive sublimate (chloride of mercury (HgCl)) with one of iodide of
potassium, just enough and no more of the latter being added to
precipitate the metal, or else the iodide of mercury is redissolved by
the excess of the precipitant. It is first of a dirty yellow, and then
gradually changes when stirred to a scarlet; if this be collected on a
filter, and washed and drained, it is a beautiful scarlet, and when some
of this substance is rubbed across a sheet of paper, a bright scarlet is
apparent, which may be rapidly changed to a lemon-yellow by heating the
paper over the flame of a spirit lamp; and the iodide of mercury is
again brought back to a scarlet colour by rubbing down the yellow
crystals with the fingers. This experiment may be repeated over and over
again with the like results. If some of the scarlet iodide of mercury is
sublimed from one bit of glass to another, it forms crystals, derived
from the right rhombic prism; when these are scratched with a pin they
change again to the scarlet state, the latter when crystallized being in
the form of the square-based octohedron.
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