The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural PhilosophyPepper, John Henry
Science
The Boy's Playbook of Science: Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy
Pepper, John Henry
Science -- Juvenile literature
Other cases of dimorphism may be mentioned--viz., with sulphur,
carbonate of lime, and lead, and many others, whilst allotropy is
curiously illustrated in the various conditions of charcoal, which, in
the more numerous examples, is black and opaque, and in another instance
transparent like water. Lamp-black is soft, but the diamond is the
hardest natural substance. The allotropic state of sulphur has been
already alluded to; phosphorus, again, exists in three modifications:
1st, Common phosphorus, which shines in the dark and emits a white
smoke. 2nd, White phosphorus. 3rd, Red or amorphous phosphorus, which
does not shine or emit white smoke when exposed to the air, and is so
altered in its properties that it may be safely carried in the pocket.
Enough evidence has therefore been offered to show that the allotropic
property is not confined to one element or compound, but is discoverable
in many bodies, and in no one more so than in the allotropic state of
the element oxygen called
OZONE.
The Greek language has again been selected by the discoverer, Schönbein,
of Basle, for the title or name of this curious modification of oxygen,
and it is so termed from [Greek: _oxein_], to smell. The name at once
suggests a marked difference between ozone and oxygen, because the
latter is perfectly free from odour, whilst the former has that peculiar
smell which is called electric, and is distinguishable whenever an
electrical machine is at work, or if a Leyden jar is charged by the
powerful Rhumkoff, or Hearder coil; it is also apparent when water is
decomposed by a current of electricity and resolved into its elements,
oxygen and hydrogen. When highly concentrated it smells like chlorine;
and the author recollects seeing the first experiments by Schönbein, in
England, at Mr. Cooper's laboratory in the Blackfriars-road. Ozone is
prepared by taking a clean empty bottle, and pouring therein a very
[Page 101] little distilled water, into which a piece of clean scraped
phosphorus is introduced, so as to expose about one-half of its diameter
to the air in the bottle, whilst the other is in contact with the water.
(Fig. 104.)
For the sake of precaution, the bottle may stand in a basin or soup
plate, so that if the phosphorus should take fire, it may be instantly
extinguished by pouring cold water into the bottle, and should this
crack and break, the phosphorus is received into the plate.
[Illustration: Fig. 104. A. A quart bottle, with the stopper loosely
placed therein. B. The stick of clean phosphorus. C. The water level
just to half the thickness of the phosphorus. D D. A soup-plate.]
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