The chemical nature of the alpha particles from radioactive substances — John Shaqi
The chemical nature of the alpha particles from radioactive substancesRutherford, Ernest
Science
The chemical nature of the alpha particles from radioactive substances
Rutherford, Ernest
Alpha rays
glass walls into a thin sheet of lead or tin, helium could always be
obtained from the metals after a few hours' bombardment.
Considering the evidence together, we conclude that the α-particle is a
projected atom of helium, which has, or in some way during its flight
acquires, two unit charges of positive electricity. It is somewhat
unexpected that the atom of a monatomic gas like helium should carry a
double charge. It must not however be forgotten that the α-particle is
released at a high speed as a result of an intense atomic explosion, and
plunges through the molecules of matter in its path. Such conditions are
exceptionably favourable to the release of loosely attached electrons
from the atomic system. If the α-particle can lose two electrons in this
way, the double positive charge is explained.
We have seen that there is every reason to believe that the α-particles,
so freely expelled from the great majority of radioactive substances,
are identical in mass and constitution and must consist of atoms of
helium. We are consequently driven to the conclusion that the atoms of
the primary radioactive elements like uranium and thorium must be built
up in part at least of atoms of helium. These atoms are released at
definite stages of the transformations at a rate independent of control
by laboratory forces. There is good reason to believe that in the
majority of cases, a single helium atom is expelled during the atomic
explosion. This is certainly the case for radium itself and its series
of products. On the other hand, Bronson has drawn attention to certain
cases, viz. the emanations of actinium and of thorium, where apparently
two and three atoms of helium respectively are expelled at one time. No
doubt these exceptions will receive careful investigation in the future.
It is of interest to note that uranium itself appears to expel two
α-particles for one from each of its products. Knowing the number of
atoms of helium expelled from the atom of each product, we can at once
calculate the atomic weights of the products. For example, in the
uranium-ionium-radium series, uranium expels two α-particles and each of
the six following α-ray products one, i.e. eight in all. Taking the
atomic weight of uranium as 238.5, the atomic weight of ionium should be
230.5, of radium 226.5, of the emanation 222.5, and so on. It is of
interest to note that the atomic weight of radium deduced in this way is
in close agreement with the latest experimental values. The atomic
weight of the end-product of radium, resulting from the transformation
of radium F (polonium) should be 238.5 – 8 x 4 = 206.5, or a value
close to that for lead. Long ago, Boltwood suggested from examination of
analyses of old uranium minerals, that lead was in all probability a
transformation product of the uranium-radium series. The coincidence of
numbers is certainly striking, but a direct proof of the production of
lead from radium will be required before this conclusion can be
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