The chemical nature of the alpha particles from radioactive substancesRutherford, Ernest
Science
The chemical nature of the alpha particles from radioactive substances
Rutherford, Ernest
Alpha rays
This proof that the α-particles consisted of actual charged atoms of
matter projected with an enormous velocity at once threw a flood of
light on radioactive processes, in particular upon another important
series of investigations which were being contemporaneously carried on
in the Laboratory at Montreal in conjunction with Mr. F. Soddy. Had time
permitted, it would have been of interest to consider in some detail the
nature of these researches which placed on a firm foundation the now
generally accepted "transformation theory" of radioactivity. From a
close examination of the substances thorium, radium, and uranium,
Rutherford and Soddy had reached the conclusion that radioactive bodies
were in a state of transformation, as a result of which a number of new
substances were produced entirely distinct in chemical and physical
character from the parent element. From the independence of the rate of
transformation of chemical and physical agencies, it was recognized that
the transformation was atomic and not molecular in character. Each of
these new bodies was shown to lose its radioactive properties according
to a definite law. Even before the discovery of the material nature of
the α-rays, it had been considered probable that the radiation from any
particular substance accompanied the breaking up of its atoms. The proof
that the α-particle was an ejected atom of matter at once strengthened
this conclusion and at the same time gave a more concrete and definite
representation of the processes occurring in radioactive matter. The
point of view reached by us at that time is clearly seen from the
following quotation, which with little alteration holds good today.
"The results obtained so far point to the conclusion that the
beginning of the succession of chemical changes taking place in
radioactive bodies is due to the emission of the α-rays, i.e. the
projection of a heavy charged mass from the atom. The portion left
behind is unstable, undergoing further chemical changes which are again
accompanied by the emission of α-rays, and in some cases also of β-rays.
"The power possessed by the radioactive bodies of apparently
spontaneously projecting large masses with enormous velocities supports
the view that the atoms of these substances are made up, in part at
least, of rapidly rotating or oscillating systems of heavy charged
bodies, large compared with the electron. The sudden escape of these
masses from their orbit may be due either to the action of internal
forces or external forces of which we have at present no knowledge."[2]
Public-domain text, read in full here on John Shaqi.
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