The chemical nature of the alpha particles from radioactive substancesRutherford, Ernest
Science
The chemical nature of the alpha particles from radioactive substances
Rutherford, Ernest
Alpha rays
These estimates of the rate of production of helium were later modified
as new and more accurate data became available. In 1905, I measured the
charge carried by the α-particles from a thin film of radium. Assuming
that each α-particle carried the ionic charge measured by J.J. Thomson,
I showed that 6.2 x 10^10 α-particles were expelled per second per gram
of radium itself and four times this number when radium was in
equilibrium with its three α-ray products. The rate of production of
helium calculated on these data was 240 cubic millimetres per gram per
year.
In the meantime, by the admirable researches of Bragg and Kleeman in
1904, our knowledge of the character of the absorption of the
α-particles by matter had been much extended. It had long been known
that the absorption of α-particles by matter was different in many
respects from that of the β-rays. Bragg showed that these differences
arose from the fact that the α-particle, on account of its great energy
of motion, was not deflected from its path like the β-particle, but
travelled in nearly a straight line, ionizing the molecules in its path.
From a thin film of matter of one kind, the α-particles were all
projected at the same speed and lost their power of producing ionization
suddenly, after traversing a certain definite distance of air. The
velocity of the α-particles in this view were reduced by their passage
through matter by equal amounts. These conclusions of Bragg were
confirmed by experiments I made by the photographic method. As a source
of rays, a thin film of radium C, deposited from the radium-emanation on
a thin wire, was used. By examining the deflection of the rays in a
magnetic field, it was found that the rays were homogeneous and were
expelled from the surface of the wire at an identical speed. By passing
the rays through a screen of mica or aluminium, it was found that the
velocity of all the α-particles were reduced by the same amount and the
issuing beam was still homogeneous.
A remarkable result was noted. All α-particles apparently lost their
characteristic properties of ionization, phosphorescence and
photographic action, at exactly the same point while they were still
moving at a speed of about 9,000 kilometres per second. At this critical
speed, the α-particle suddenly vanishes from our ken and can no longer
be followed by the methods of observation at our command.
The use of a homogeneous source of α-rays like radium C at once
suggested itself as affording a basis for a more accurate determination
of the value of _e/m_ for the α-particle and for seeing whether the value
was consistent with the view that the α-particle was a charged atom of
helium. In the course of a long series of experiments, I proved that the
α-particles, whether expelled from radium, thorium or actinium, were
identical in mass and must consist of the same kind of matter.
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