The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
When heated to a little above 140° Fahr., an absorption of water takes
place through the enveloping membrane of the granules, they swell
considerably, and the mixture becomes pasty or viscous. If this paste
be largely diluted with water, the swollen granules still remain as
separate bodies and slowly sink, though a considerable exosmosis of the
true starch has occurred, as shown by the thickening of the water. I
suppose that in their original state the enveloping membrane is much
folded, and that these folds form the curious marking of concentric
rings which constitutes the characteristic microscopic structure of
starch granules, and that when cooked, at the temperature named, the
very delicate membrane becomes fully distended by the increased bulk of
the hydrated and diluted starch, and thus the rings disappear.
A very little mechanical violence, mere stirring, now breaks up these
distended granules, and we obtain the starch paste so well known to the
laundress, and to all who have seen cooked arrowroot. If this paste be
dried by evaporation it does not regain its former insolubility, but
readily dissolves in hot or cold water. This is what I should describe
as cooked starch.
If the heat is now raised from 140° to the boiling point, and the
boiling continued, the gelatinous mass becomes thicker and thicker;
and if there are more than fifty parts of water to one of starch a
separation takes place, the starch settling down with its fifty parts
of water, the excess of water standing above it. Carefully dried starch
may be heated to above 300° without becoming soluble, but at 400° a
remarkable change commences. The same occurs to ordinary commercial
starch at 320°, the difference evidently depending on the water
retained by it. If the heat is continued a little beyond this it is
converted into _dextrin_, otherwise named ‘British gum,’ ‘gommeline,’
‘starch gum,’ and ‘Alsace gum,’ from its resemblance to gum-arabic,
for which it is now very extensively substituted. Solutions of this in
bottles are sold in the stationers’ shops under various names for desk
uses.
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