The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
The remarkable feature of this conversion of starch into dextrin is,
that it is accompanied by no change of chemical composition. Starch
is composed of six equivalents of carbon, ten of hydrogen, and five
of oxygen—C_{6}H_{10}O_{5}, _i.e._ six of carbon and five of water or
its elements. Dextrin has exactly the same composition; so also has
gum-arabic when purified. But their properties differ considerably.
Starch, as everybody knows, when dried is white and opaque and
pulverent; dextrin, similarly dried, is transparent and brittle;
gum-arabic the same. If a piece of starch, or a solution of starch, is
touched by a solution of iodine, it becomes blue almost to blackness,
if the solution is strong; no such change occurs when the iodine
solution is added to dextrin or gum. A solution of dextrin when mixed
with potash changes to a rich blue colour when a little sulphate of
copper is added; no such effect is produced by gum-arabic, and thus
we have an easy test for distinguishing between true and fictitious
gum-arabic.
The technical name for describing this persistence of composition with
changes of properties is _isomerism_, and bodies thus related are said
to be _isomeric_ with each other. Another distinguishing characteristic
of dextrin is that it produces a right-handed rotation on a ray of
polarised light, hence its name, from _dexter_, the right.
The conversion of starch into dextrin is a very important element of
the subject of vegetable cooking, inasmuch as starch food cannot be
assimilated until this conversion has taken place, either before or
after we eat it. I will therefore describe other methods by which this
change may be effected.
If starch be boiled in a dilute solution of almost any acid, it is
converted into dextrin. A solution containing less than one per cent.
of sulphuric or nitric acid is sufficiently strong for this purpose.
One method of commercial manufacture (Payen’s) is to moisten 10 parts
of starch with 3 of water, containing 1/150th of its weight of nitric
acid, spreading the paste upon shelves, allowing it to dry in the air,
and then heating it for an hour-and-a-half at about 240° Fahr.
But the most remarkable and interesting agent in effecting this
conversion is _diastase_. It is one of those mysterious compounds which
have received the general name of ‘ferments.’ They are disturbers of
chemical peace, molecular agitators that initiate chemical revolutions,
which may be beneficent or very mischievous. The morbific matter of
contagious diseases, the venom of snake-bite, and a multitude of other
poisons, are ferments. Yeast is a familiar example of a ferment, and
one that is the best understood.
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