The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
But the practical cook may say, ‘This is wrong, for the fat in my
frying-pan does boil. I see it boil, and I hear it boil.’ The reply to
this is, that the lard, or dripping, or butter that you put into your
frying-pan is oil mixed with water, and that it is not the oil but the
water that you see boiling. To prove this, take some fresh lard, as
usually supplied, and heat it in any convenient vessel, raising the
temperature gradually. Presently it will begin to splutter. If you
try it with a thermometer you will find that this spluttering-point
agrees with the boiling-point of water, and if you use a retort you may
condense and collect the splutter-matter, and prove it to be water.
So long as the spluttering continues the temperature of the melted
fat, _i.e._ the oil, remains about the same, the water vapour carrying
away the heat. When all the water is driven off the liquid becomes
quiescent, in spite of its temperature rising from 212° to above 400°,
when a pungent smoky vapour comes off and the oil grows darker; this
vapour is not vapour of lard, but vapour of separated and recombined
constituents of the lard, which is now suffering dissociation, the
volatile products passing off while the non-volatile carbon (_i.e._
lard-charcoal) remains behind, colouring the liquid. If the heating
be continued, a residuum of this carbon, in the form of soft coke or
charcoal, will be all that remains in the heated vessel.
We may now understand what happens when something humid—say a sole—is
put into a frying-pan which contains fat heated above 212°. Water, when
suddenly heated above its boiling-point, is a powerful explosive, and
may be very dangerous, simply because it expands to 1,728 times its
original bulk when converted into steam. Steam-engine boilers and the
boilers of kitchen stoves sometimes explode by becoming red-hot while
dry, and then receiving a little water which suddenly expands to steam.
The noise and spluttering that is started immediately the sole is
immersed in the hot fat is due to the explosion of a multitude of small
bubbles formed by the confinement of the suddenly expanding steam in
the viscous fat, from which it releases itself with a certain degree
of violence. It is evident that to effect this amount of eruptive
violence, the temperature must be considerably above the boiling-point
of the exploding water. If it were only just at the boiling-point, the
water would boil quietly.
Public-domain text, read in full here on John Shaqi.
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