The Chemistry of CookeryWilliams, W. Mattieu (William Mattieu)
Science
The Chemistry of Cookery
Williams, W. Mattieu (William Mattieu)
Cooking
It is the yielding back of the atmospheric gases which the water
has dissolved or condensed within itself. These bubbles have been
collected, and by analysis proved to consist of oxygen, nitrogen, and
carbonic acid, obtained from the air; but in the water they exist by no
means in the same proportions as originally in the air, nor in constant
proportions in different samples of water. I need not here go into the
quantitative details of these proportions, nor the reasons of their
variation, though they are very interesting subjects.
Proceeding with our investigation, we shall find that the bubbles
continue to form and rise until the water becomes too hot for the
finger to bear immersion. At about this stage something else begins to
occur. Much larger bubbles, or rather blisters, are now formed on the
bottom of the vessel, immediately over the flame, and they continually
collapse into apparent nothingness. Even at this stage a thermometer
immersed in the water will show that the boiling-point is not reached.
As the temperature rises, these blisters rise higher and higher,
become more and more nearly spherical, finally quite so, then detach
themselves and rise towards the surface; but the first that make this
venture perish in the attempt—they gradually collapse as they rise, and
vanish before reaching the surface. The thermometer now shows that the
boiling-point is nearly reached, but not quite. Presently the bubbles
rise completely to the surface and break there. Now the water is
boiling, and the thermometer stands at 212° Fahr. or 100° Cent.
With the aid of suitable apparatus it can be shown that the atmospheric
gases above named continue to be given off along with the steam for a
considerable time after the boiling has commenced; the complete removal
of their last traces being a very difficult, if not an impossible,
physical problem.
After a moderate period of boiling, however, we may practically regard
the water as free from these gases. In this condition I venture to call
it cooked water. Our experiment so far indicates one of the differences
between cooked and raw water. The cooked water has been deprived of
the atmospheric gases that the raw water contained. By cooling some
of the cooked water and tasting it, the difference of flavour is very
perceptible; by no means improved, though it is quite possible to
acquire a preference for this flat, tasteless liquid.
If a fish be placed in such cooked water it swims for a while with its
mouth at the surface, for just there is a film that is reacquiring its
charge of oxygen, &c., by absorbing it from the air; but this film is
so thin, and so poorly charged, that after a short struggle the fish
dies for lack of oxygen in its blood; drowned as truly and completely
as an air-breathing animal when immersed in any kind of water.
Public-domain text, read in full here on John Shaqi.
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