The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
silk contains nitrogen. Thirdly, I will heat some fur with soda-lime.
Ammonia escapes, giving all the reactions described under silk. Hence
fur, wool, etc., contain nitrogen. As regards proofs of all three of
these classes of fibres containing carbon, hydrogen, and oxygen, the
char they all leave behind on heating in a closed vessel is the carbon
itself present. For the hydrogen and oxygen, a perfectly dry sample of
any of these fabrics is taken, of course in quantity, and heated
strongly in a closed vessel furnished with a condensing worm like a
still. You will find all give you water as a condensate--the vegetable
fibre, acid water; the animal fibres, alkaline water from the ammonia.
The presence of water proves both hydrogen and oxygen, since water is a
compound of these elements. If you put a piece of potassium in contact
with the water, the latter will at once decompose, the potassium
absorbing the oxygen, and setting free the hydrogen as gas, which you
could collect and ignite with a match, when you would find it would
burn. That hydrogen was the hydrogen forming part of your cotton, silk,
or wool, as the case might be. We must now attack the question of
sulphur. First, we prepare a little alkaline lead solution (sodium
plumbate) by adding caustic soda to a solution of lead acetate or sugar
of lead, until the white precipitate first formed is just dissolved.
That is one of our reagents; the other is a solution of a red-coloured
salt called nitroprusside of sodium, made by the action of nitric acid
on sodium ferrocyanide (yellow prussiate). The first-named is very
sensitive to sulphur, and turns black directly. To show this, we take a
quantity of flowers of sulphur, dissolve in caustic soda, and add to the
lead solution. It turns black at once, because the sulphur unites with
the lead to form black sulphide of lead. The nitroprusside, however,
gives a beautiful crimson-purple coloration. Now on taking a little
cotton and heating with the caustic alkaline lead solution, if sulphur
were present in that cotton, the fibre would turn black or brown, for
the lead would at once absorb such sulphur, and form in the fibre soaked
with it, black sulphide of lead. No such coloration is formed, so cotton
does not contain sulphur. Secondly, we must test silk. Silk contains
nitrogen, like wool, but does it contain sulphur? The answer furnished
by our tests is--no! since the fibre is not coloured brown or black on
heating with the alkaline lead solution. Thirdly, we try some white
Berlin wool, so that we can easily see the change of colour if it takes
place. In the hot lead solution the wool turns black, lead sulphide
being formed. On adding the nitroprusside solution to a fresh portion of
wool boiled with caustic soda, to dissolve out the sulphur, a splendid
purple coloration is produced. Fur and hair would, of course, do the
same thing. Lead solutions have been used for dyeing the hair black; not
caustic alkaline solutions like this, however.
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